Cu-Based Sintered Sliding Material for Wear and Dimensional Stability

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Solution Overview

Problem

Existing Cu-based sintered bearings face issues with wear and dimensional stability under high rotation rates and surface pressures, with excessive wear and dimensional changes due to spinodal decomposition and phosphorus-induced sintering effects.

Innovation Solution

A Cu-based sintered body is developed by sintering Cu-Ni alloy grains with controlled amounts of Ni, Sn, and P, incorporating grain boundary phases with Ni and P as main components, and free graphite, which reduces dimensional changes and enhances strength and wear resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If spinodal decomposition treatment is applied to strengthen Cu-Ni-Sn alloy, then hardness is improved, but wear resistance deteriorates due to excessive hardness causing mismatch with mating shaft

Engineering Contradiction:
ImprovehardnessVSAvoidwear resistance
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies spinodal decomposition treatment with controlled parameters (temperature range 400-600°C, time 1-24 hours) to achieve optimal hardness (HB 80-150) that balances strength and wear resistance. By precisely controlling the decomposition parameters, the material achieves a hardness level that provides wear resistance without excessive hardness that would cause mismatch with mating shafts.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite microstructure consisting of Cu-Ni-Sn alloy matrix with dispersed Ni3Sn4 intermetallic compounds formed through spinodal decomposition. This composite structure combines the ductility of the Cu-based matrix with the hardness of Ni3Sn4 particles, achieving both strength and wear resistance.

Inventive Principle:
Principle #40Composite materials

2Reliability

If P is added to form Ni-P phases to improve wear resistance, then wear resistance is improved, but dimensional stability deteriorates due to large dimensional change and variation during sintering

Engineering Contradiction:
Improvewear resistanceVSAvoiddimensional stability
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent optimizes the phosphorus content to a specific range (0.01-3.0 wt%) to achieve the desired balance. Within this range, P forms sufficient Ni-P phases for wear resistance while limiting excessive sintering promotion that would cause large dimensional changes. The controlled composition parameter resolves the contradiction between wear resistance and dimensional stability.

Inventive Principle:
Principle #35Parameter changes

3Stress or pressure

If rolling bearing is used to support high surface pressure or high rotation rate, then load capacity is improved, but cost deteriorates

Engineering Contradiction:
Improveload capacityVSAvoidcost
Core Design Contradiction:
Stress or pressureVSEase of manufacture

Solution Approach 1:

The patent employs a sintered Cu-Ni-Sn alloy bearing material that is more cost-effective than traditional rolling bearings. The sintered structure with controlled porosity (10-30%) provides adequate load capacity for high surface pressure and high rotation rate applications at a lower cost, accepting some limitations in service life compared to rolling bearings.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent creates a composite sintered structure with Cu-Ni-Sn alloy grains, Ni3Sn4 intermetallic compounds, and controlled porosity. This composite material achieves sufficient mechanical properties and tribological performance for high load and high speed applications while maintaining cost-effectiveness compared to precision rolling bearings.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a sintered body with improved wear resistance and dimensional stability, suitable for high rotation rates and surface pressures, while maintaining productivity and cost-effectiveness.

Implementation Method 1

a sintered material obtained by sintering Cu-Ni-based alloy grains

Methodology Applied
Scientific EffectSintering: Sintering

Implementation Method 2

wear characteristics during sliding are improved by including grain boundary phases containing Ni and P as main components

Methodology Applied
Scientific EffectTribology: Friction

Data Source

PatentEP3424623B1Cu-based sintered sliding material and production method therefor
Publication Date: 2023.03.29 DIAMET CORP
  • EP3424623B1 patent drawingFigure 1~2

AI summary

The Cu-based sintered sliding material of the present invention has a composition including, by mass%, 7% to 35% of Ni, 1% to 10% of Sn, 0.9% to 3% of P, and 0.5% to 5% of C, with a remainder of Cu and inevitable impurities, wherein the Cu-based sintered sliding material includes a sintered body including: alloy grains that contain Sn and C and contain a Cu-Ni-based alloy as a main component; grain boundary phases that contain Ni and P as main components and are dispersedly distributed in grain boundaries of the alloy grains; and free graphite that intervenes at the grain boundaries of the alloy grains, the Cu-based sintered sliding material has a structure in which pores are dispersedly formed in the grain boundaries of the alloy grains, and an amount of C in a metal matrix including the alloy grains and the grain boundary phases is, by mass%, 0.02% to 0.20%.