Cubane Organic Compounds for OLED Efficiency and Lifetime

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Solution Overview

Problem

Current organic electroluminescent devices, particularly those using phosphorescent or fluorescent emitters, face challenges in efficiency, operating voltage, and lifetime, with a need for improved matrix materials, hole conductor materials, and electron transport materials that also ensure high color purity and ease of processing.

Innovation Solution

Development of specific organic compounds with cubane structures that can be used as matrix materials, hole conductor materials, or electron transport materials in organic electroluminescent devices, enhancing their efficiency, voltage, and lifetime while maintaining high color purity and ease of processing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional matrix materials, hole conductor materials, or electron transport materials are used in organic electroluminescent devices, then the devices can operate, but the lifetime, efficiency, and operating voltage performance are insufficient

Engineering Contradiction:
Improvedevice lifetimeVSAvoiddevice efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent modifies the molecular structure of matrix materials, hole conductor materials, and electron transport materials by introducing specific chemical groups and substituents (e.g., formulas I-1 to I-10 with various R1-R6 substituents) to optimize their electronic and optical properties. This structural parameter change enables simultaneous improvement in device lifetime, efficiency, and operating voltage through enhanced material performance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent develops composite material systems where cubane-based compounds are combined with other organic materials to form functional layers in OLEDs. These composite materials leverage the unique properties of cubane structures (high stability, rigid framework) combined with other materials to achieve superior device performance across multiple parameters simultaneously

Inventive Principle:
Principle #40Composite materials

2Use of energy by stationary object

If conventional materials are used, then device operation is achieved, but operating voltage remains high

Engineering Contradiction:
Improveoperating voltageVSAvoidmaterial processing
Core Design Contradiction:
Use of energy by stationary objectVSEase of manufacture

Solution Approach 1:

The patent optimizes the HOMO and LUMO energy levels of matrix materials, hole conductor materials, and electron transport materials through molecular design (formulas I-1 to I-10 with可调 substituents). This energy level parameter change reduces the voltage required for charge injection and transport, lowering operating voltage while maintaining ease of manufacturing through conventional deposition techniques

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If materials with high color purity are used, then color quality improves, but device efficiency and lifetime may be compromised

Engineering Contradiction:
Improvecolor purityVSAvoiddevice lifetime
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent introduces specific functional groups and substituents at particular positions in the molecular structures (formulas I-1 to I-10 with defined R1-R6 positions) to achieve localized optimization. This local quality modification enables high color purity through controlled emission wavelengths while maintaining overall molecular stability and device lifetime through the robust cubane framework

Inventive Principle:
Principle #3Local quality

Data Source

PatentUS11917906B2Compounds that can be used in an organic electronic device
Publication Date: 2024.02.27 MERCK PATENT GMBH
  • US11917906B2 patent drawing
  • US11917906B2 patent drawing
  • US11917906B2 patent drawing

AI summary

The invention relates to compounds that can be used in an organic electronic device as an active compound, in particular for use in electronic devices. The invention further relates to a process for preparing the compounds according to the invention, and to electronic devices comprising the same.