CuNiSn Intermediate Layer for Sliding Bearing Diffusion Barrier

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Solution Overview

Problem

Previous plain bearing composite materials face challenges with nickel-based diffusion barrier layers, which are difficult to deposit and prone to galling, leading to thin intermediate layers and thick overlays, affecting manufacturability and wear resistance.

Innovation Solution

A plain bearing composite material with a copper-tin or copper-zinc alloy bearing metal layer, a CuNiSn intermediate layer formed by PVD, and a thicker AlSn overlay, where the intermediate layer acts as both a diffusion barrier and improves tribological properties, reducing galling and wear while enhancing adaptability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If nickel-based diffusion barrier layers are used, then tin diffusion is prevented, but deposition difficulty and galling tendency increase

Engineering Contradiction:
Improvediffusion barrier functionVSAvoiddeposition difficulty
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent changes the material composition parameters of the intermediate layer from traditional nickel-based alloys to copper-nickel-tin alloys with specific compositional ranges (Cu: 70-95 wt%, Ni: 3-20 wt%, Sn: 3-10 wt%). This parameter change enables the layer to maintain diffusion barrier functionality while improving depositability through PVD processes and reducing galling tendency.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite intermediate layer combining copper, nickel, and tin elements with a controlled gradient structure. The copper-nickel-tin composite material exhibits synergistic properties: copper provides base metal compatibility, nickel offers diffusion barrier characteristics, and tin enhances surface properties and reduces galling, while the composite structure improves overall manufacturability.

Inventive Principle:
Principle #40Composite materials

2Reliability

If nickel-based intermediate layers are used, then tin diffusion is blocked, but galling increases requiring thicker overlays

Engineering Contradiction:
Improvediffusion barrier functionVSAvoidgalling tendency
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent modifies the compositional parameters of the intermediate layer by incorporating tin (3-10 wt%) alongside nickel (3-20 wt%) in a copper matrix. This parameter change fundamentally alters the tribological properties, reducing galling tendency while preserving the diffusion barrier function, thereby eliminating the need for excessive overlay thickness.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent converts the potential harm of nickel-based layers (galling tendency) into a benefit by adding tin to the composition. The tin content transforms the intermediate layer's surface properties, making it more compatible with the tin-containing overlay and reducing galling, while the nickel component continues to provide diffusion barrier protection.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Productivity

If intermediate layer thickness is reduced to 1-1.5 μm, then deposition time is reduced, but galling and wear resistance worsen

Engineering Contradiction:
Improvedeposition speedVSAvoidgalling and wear
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the material parameters of the intermediate layer to copper-nickel-tin alloys, which have improved depositability through PVD processes. This enables efficient deposition at thicknesses of 1-10 μm while simultaneously reducing galling tendency and improving wear resistance, thus resolving the contradiction between deposition speed and performance.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent converts the limitation of thin intermediate layers (poor wear resistance and galling) into an advantage by using copper-nickel-tin composition. The specific alloying elements and their ratios provide both rapid depositability and superior tribological properties, making thin layers effective where traditional nickel layers failed.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

4Strength

If harder bearing metal layers are used, then wear resistance improves, but seizure tendency increases and adaptability decreases

Engineering Contradiction:
Improvewear resistanceVSAvoidadaptability and embedding ability
Core Design Contradiction:
StrengthVSAdaptability or versatility

Solution Approach 1:

The patent changes the hardness parameter of the bearing metal layer by using lower-alloy copper-tin or copper-zinc compositions instead of high-alloy hard materials. This parameter change reduces seizure tendency and improves adaptability while compensating for wear resistance through the optimized copper-nickel-tin intermediate layer and tin-containing overlay configuration.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces the copper-nickel-tin intermediate layer as a mediator between the softer bearing metal layer and the tin-containing overlay. This intermediate layer with its specific composition (Cu: 70-95 wt%, Ni: 3-20 wt%, Sn: 3-10 wt%) provides the necessary wear resistance and surface properties, allowing the bearing metal layer to remain soft and adaptable while preventing direct contact between dissimilar materials.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution improves manufacturability, adaptability, and wear resistance by using a softer CuNiSn intermediate layer that reduces seizure and wear, allowing for thicker deposition and better particle compatibility, while maintaining low costs and good emergency running behavior.

Implementation Method 1

the intermediate layer (8) formed by physical vapor deposition (PVD) of CuNi(3-20)Sn(3-10)...which forms a diffusion barrier for tin

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Implementation Method 2

with a directly tin-containing overlay formed on the intermediate layer by physical vapor deposition (PVD)...the intermediate layer (8) formed by physical vapor deposition (PVD)

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Data Source

PatentEP2513356B1Sliding bearing composite
Publication Date: 2013.12.11 GLEITLAGER
  • EP2513356B1 patent drawing

AI summary

The invention relates to a sliding bearing composite (2) having a support layer (4), in particular of steel, having a bearing metal layer (6) which is applied thereto and is composed of a bearing material based on a copper-tin or copper-zinc alloy and has a thickness of at least 100 Mm, with an intermediate layer (8) and a tin-containing sliding layer (10) formed directly on top of the intermediate layer (8) by physical vapour deposition (PVD), where the bearing material is formed by a copper-tin or copper-zinc alloy containing not more than 6% by weight of tin or not more than 25% by weight of zinc and the intermediate layer (8) is formed by physical vapour deposition (PVD) of CuNi(3-20)Sn(3-10), optionally with further constituents, and has a thickness of 1-10 µm.