Cup-Shaped DRAM Capacitor Electrode With TiN/SiN Etch Control

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Solution Overview

Problem

Dynamic random access memories (DRAM) capacitors face challenges in increasing capacitance while managing leakage current due to reduced critical dimensions, necessitating new capacitor geometries and materials.

Innovation Solution

A method for forming a bottom electrode structure in capacitors, comprising a cup-shaped first bottom electrode layer with alternating titanium nitride and silicon nitride layers, and a second bottom electrode layer with titanium nitride, where the dielectric and top electrodes conformally cover the internal and external surfaces, enhancing etch resistance and contact areas.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Volume of moving object

If the capacitor dimensions are reduced to increase integration density, then the device size is reduced, but the leakage current increases

Engineering Contradiction:
Improvecapacitor dimensionsVSAvoidleakage current
Core Design Contradiction:
Volume of moving objectVSObject-generated harmful factors

Solution Approach 1:

The patent applies local quality by creating a cup-shaped bottom electrode geometry with enhanced sidewall contact area, and by using alternating TiN/SiN layers with different etch resistance properties in specific regions. The SiN layers provide higher etch resistance at the sidewalls to maintain contact area, while TiN layers provide conductivity. This localized differentiation of material properties and geometric features addresses the leakage issue without requiring overall capacitor size increase.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent employs composite materials by stacking alternating layers of titanium nitride (TiN) and silicon nitride (SiN) to form the bottom electrode. TiN provides electrical conductivity while SiN provides higher etch resistance. This composite structure maintains low leakage current by preserving the electrode-dielectric contact area during etching processes, even as capacitor dimensions are reduced.

Inventive Principle:
Principle #40Composite materials

2Object-generated harmful factors

If new capacitor geometries and materials are developed to reduce leakage current, then the leakage current is reduced, but the device complexity increases

Engineering Contradiction:
Improveleakage currentVSAvoidcapacitor structure
Core Design Contradiction:
Object-generated harmful factorsVSDevice complexity

Solution Approach 1:

The patent segments the bottom electrode into alternating thin layers of TiN and SiN, with each layer serving a specific function. The TiN layers provide conductivity while SiN layers provide etch resistance. This segmentation allows the complex performance requirements (low leakage, good conductivity, etch resistance) to be met through layered composition rather than a single complex structure.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent changes material parameters by selecting TiN and SiN with complementary properties - TiN for conductivity and SiN for etch resistance. The layer thicknesses are optimized (total TiN thickness greater than total SiN thickness) to balance electrical performance with etch resistance. These parameter optimizations reduce leakage current while keeping the fabrication process compatible with existing CMOS technology.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in a capacitor with higher capacitance while maintaining low leakage current, as the etch resistance of the outer portion is higher than the inner portion, allowing the outer radius to remain and the inner radius to increase, maximizing contact areas with the dielectric layer.

Implementation Method 1

depositing a plurality of titanium nitride layers and a plurality of silicon nitride layers alternately and conformally in the opening to form a bottom electrode

Methodology Applied
Scientific EffectPhysical Vapour Deposition: Physical Vapour Deposition

Data Source

PatentUS20240178267A1Capacitor and fabricating method thereof
Publication Date: 2024.05.30 NAN YA TECH
  • US20240178267A1 patent drawing
  • US20240178267A1 patent drawing
  • US20240178267A1 patent drawing

AI summary

A capacitor for a memory device includes a substrate, a bottom electrode, a dielectric layer, and a top electrode. The bottom electrode includes a first bottom electrode layer and a second bottom electrode layer. The first bottom electrode layer is disposed on the substrate. The first bottom electrode layer has a cup shape. The first bottom electrode layer includes a plurality of titanium nitride layers and a plurality of silicon nitride layers that are stacked alternately. The second bottom electrode layer has a cup shape. The second bottom electrode layer includes titanium nitride. An external surface of the second bottom electrode layer contacts an internal surface of the first bottom electrode layer. The dielectric layer conformally covers an internal surface of the second bottom electrode layer. A top electrode conformally covers the dielectric layer.