Curable Coating Composition with Branched Siloxanes for Anti-Adhesive Performance

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Solution Overview

Problem

Existing coatings lack effective anti-adhesive properties while maintaining other protective functions, leading to issues such as biofouling, mechanical stress vulnerability, and limited resistance to soiling and ice adhesion.

Innovation Solution

A curable composition containing a film-forming polymer and organo-modified, branched siloxanes with specific structural formulas, which provide enhanced anti-adhesive activity by forming a surface that prevents or reduces adhesion of various contaminants without compromising mechanical strength or other properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If conventional coatings are used for surface protection, then basic protective functions are provided, but anti-adhesive properties are insufficient leading to biofouling and soiling

Engineering Contradiction:
Improvebiofouling and soiling resistanceVSAvoidanti-adhesive property
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent applies composite materials by combining film-forming polymers with organo-modified branched siloxanes in a single coating composition. The siloxanes contain specific structural units (M, M', D, D', T, Q) that create anti-adhesive surfaces while the polymer matrix provides mechanical integrity. This composite approach enables simultaneous achievement of protective functions and anti-adhesive properties without compromising either aspect.

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If coatings are designed to provide anti-adhesive properties, then biofouling is reduced, but mechanical strength and resistance to mechanical stress may be compromised

Engineering Contradiction:
Improvebiofouling resistanceVSAvoidmechanical strength
Core Design Contradiction:
Object-affected harmful factorsVSStrength

Solution Approach 1:

The patent applies local quality by creating a differentiated structure where the siloxane-modified polymer chains concentrate anti-adhesive functional groups at the coating surface, while the bulk polymer matrix maintains mechanical strength. The branched siloxane structures with specific units (M, M', D, D', T, Q) are positioned to provide anti-adhesive activity at the interface, while the overall coating architecture preserves structural integrity and resistance to mechanical stress.

Inventive Principle:
Principle #3Local quality

3Object-affected harmful factors

If existing coating formulations are used, then basic protective functions are maintained, but resistance to ice adhesion and mechanical stress is limited

Engineering Contradiction:
Improveice adhesion resistanceVSAvoidresistance to mechanical stress
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent applies parameter changes by modifying the chemical structure and composition parameters of the coating formulation. Specifically, it incorporates organo-modified branched siloxanes with controlled molecular structures (defined by units M, M', D, D', T, Q and their respective substituents) to alter surface properties for ice resistance while maintaining mechanical performance through optimized polymer-siloxane ratios and crosslinking parameters.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The coatings exhibit improved anti-adhesive properties, including reduced biofouling, enhanced mechanical resistance, and effective anti-icing performance, while maintaining or improving other protective functions.

Implementation Method 1

The coatings exhibit improved anti-adhesive properties, including reduced biofouling, enhanced mechanical resistance, and effective anti-icing performance

Methodology Applied
Scientific EffectLow surface energy: Surface Tension

Data Source

PatentUS12054635B2Curable composition for coatings having an anti-adhesive property
Publication Date: 2024.08.06 EVONIK OPERATIONS GMBH
  • US12054635B2 patent drawing
  • US12054635B2 patent drawing

AI summary

Curable composition for producing coating systems having an anti-adhesive property containing at least one film-forming polymer and at least one organo-modified, branched siloxane of formula (I) or mixtures thereof.