Curable Composition for Electronic Circuits
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Solution Overview
Problem
The existing curable composition for electronic circuits has insufficient elongation properties, leading to a risk of cracking under temperature fluctuations, compromising both electrical insulation and durability.
Innovation Solution
A curable composition incorporating a branched polyolefin structure, saturated cycloalkyl(meth)acrylate monomers, and saturated chain alkyl(meth)acrylate monomers, along with an isocyanate monomer, which can be cured by light and moisture, enhancing both electrical insulation and elongation properties.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Reliability
If a curable composition uses conventional urethane resin with hydrogenated butadiene-based skeleton and monofunctional (meth)acrylate monomer, then electrical insulation properties are achieved, but elongation properties are insufficient
Solution Approach 1:
The patent uses a composite resin system combining polyurethane resin with specific (meth)acrylate monomers (cycloalkyl and chain alkyl types) to achieve both electrical insulation and elongation properties. The composite structure allows the material to maintain electrical properties while gaining mechanical flexibility and elongation capability through the synergistic effect of different polymer components.
Solution Approach 2:
The patent modifies the chemical composition parameters by specifying precise ratios of (meth)acrylate monomers (cycloalkyl type: 40-80 parts, chain alkyl type: 20-60 parts) relative to the polyurethane resin. This parameter optimization enables the cured product to achieve both good electrical insulation and sufficient elongation properties simultaneously.
2Reliability
If the cured product has good electrical insulation, then it can be used in electronic circuits, but it is prone to cracking under temperature fluctuations
Solution Approach 1:
The patent adjusts the chemical composition parameters by incorporating specific (meth)acrylate monomers in controlled amounts, which changes the thermal and mechanical properties of the cured product. This parameter modification enables the material to maintain electrical insulation while improving resistance to thermal stress and cracking.
Solution Approach 2:
The composite resin system combines polyurethane with (meth)acrylate monomers to create a material that has both electrical insulation properties and thermal stability. The composite structure provides a balance between electrical performance and resistance to thermal-induced cracking.
3Reliability
If the curable composition is cured by both light and moisture, then complete curing is achieved, but the formulation complexity increases
Solution Approach 1:
The patent employs a multi-functional curing system where the same curable composition can be cured by both light (photopolymerization) and moisture (polymerization). This universal curing capability allows complete curing under different environmental conditions without requiring separate formulation systems, thereby achieving reliable curing while managing formulation complexity through a unified approach.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The composition achieves a cured product with improved elongation properties and electrical insulation, providing better thermal stability and reliability against temperature fluctuations.
Implementation Method 1
the monofunctional (meth)acrylate monomers described above react with each other by the irradiation with light such as ultraviolet rays to be polymerized
Implementation Method 2
the isocyanate groups of the urethane resin react with each other by moisture in air to allow polymerization to proceed
Data Source
AI summary
Provided is a curable composition including: a curable oligomer having, in its molecule, a branched polyolefin structure and a (meth)acryloyl group; a saturated cycloalkyl (meth)acrylate monomer having, in its molecule, a saturated cyclic hydrocarbon structure and a (meth)acryloyl group; and a saturated chain alkyl (meth)acrylate monomer having, in its molecule, a saturated chain hydrocarbon structure and a (meth)acryloyl group.


