Curable Composition with Kaolinite and Quartz for Water-Resistant Adhesiveness

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Solution Overview

Problem

Current curable compositions with reactive silicon groups face challenges in achieving high environmental compatibility and water-resistant adhesiveness, especially when bonding to low-polar and porous substrates, and there is a need for alternatives to urethane-based adhesives due to health and environmental concerns.

Innovation Solution

A curable composition comprising an organic polymer with reactive silicon groups and a bound substance of kaolinite and quartz, which provides a cured product with high water-resistant adhesiveness and strength, while being environmentally compatible.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If conventional urethane-based adhesives are used for woodworking, then adhesiveness is achieved, but harmful isocyanate groups are present that adversely influence human health and environment

Engineering Contradiction:
Improvehuman health and environmental safetyVSAvoidadhesiveness
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The invention changes the chemical composition parameters by using organic polymers with reactive silicon groups instead of isocyanate-based polymers. This substitution maintains the crosslinking mechanism (through siloxane bond formation) while eliminating harmful isocyanate groups, thus resolving the contradiction between safety and adhesiveness

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite adhesive system combining organic polymers with reactive silicon groups and inorganic fillers (such as colloidal silica). This composite approach enhances water-resistant adhesiveness while maintaining environmental compatibility by replacing harmful conventional adhesives

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If organic polymers with reactive silicon groups are used to improve environmental compatibility, then water-resistant adhesiveness to low-polar and porous substrates is insufficient

Engineering Contradiction:
Improveenvironmental compatibilityVSAvoidwater-resistant adhesiveness
Core Design Contradiction:
Object-affected harmful factorsVSStrength

Solution Approach 1:

The invention optimizes parameters including the type of reactive silicon groups (hydrolyzable silyl groups), molecular weight and structure of organic polymers, and addition of inorganic fillers. These parameter adjustments enhance water-resistant adhesiveness to low-polar and porous substrates while preserving environmental compatibility

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention develops composite materials combining organic polymers with reactive silicon groups and inorganic components (colloidal silica, bound substances of kaolinite and quartz). This composite structure improves water-resistant adhesiveness and strength while maintaining environmental compatibility

Inventive Principle:
Principle #40Composite materials

3Strength

If epoxy resin is added to curable composition to improve strength and water-resistant adhesiveness, then environmental compatibility is compromised due to adverse health influences

Engineering Contradiction:
Improvewater-resistant adhesivenessVSAvoidenvironmental compatibility
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The invention changes the chemical composition by substituting epoxy resin with organic polymers containing reactive silicon groups. The silane crosslinking mechanism provides comparable or superior water-resistant adhesiveness and strength while eliminating the harmful effects of epoxy resin, thus resolving the contradiction between strength and environmental compatibility

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition cures at room temperature, offering a strong and water-resistant adhesive bond to various substrates, including low-polar and porous materials, and is free from harmful chemicals, enhancing environmental compatibility.

Implementation Method 1

an organic polymer containing at least one reactive silicon group in a molecule is crosslinked by the formation of a siloxane bond, which is accompanied by hydrolysis and the like of a silyl group due to moisture

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Implementation Method 2

crosslinked by the formation of a siloxane bond

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 3

a composition containing at least an organic polymer containing a reactive silicon group and a bound substance of kaolinite and quartz can provide a cured product having a sufficiently high water-resistant adhesiveness

Methodology Applied
Scientific EffectAdhesion: Adhesive

Data Source

PatentEP3098267B2Curable composition
Publication Date: 2022.05.25 KANEKA CORP
  • EP3098267B2 patent drawing
  • EP3098267B2 patent drawing

AI summary

The present invention relates to a curable composition containing an organic polymer containing a reactive silicon group (A), and a bound substance of kaolinite and quartz (B). The curable composition of the present invention has high environmental compatibility and cures at room temperature, and a cured product obtained therefrom affords a cured product having high water-resistant adhesiveness, preferably a cured product having high strength and high water-resistant adhesiveness.