Curable Composition with Multiple Latent Curing Agents

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Solution Overview

Problem

Existing adhesives for motor vehicle body shop processes require higher temperatures for curing, which is energy-intensive and not environmentally friendly, and do not meet the demands for lower temperature curing while maintaining properties like hardness, elongation, and shear strength.

Innovation Solution

A curable composition comprising an elastomer, epoxy resin, latent curing agent, filler, thermoplastic resin, and crosslinking agent, with the latent curing agent being a combination of two or more latent curing agents, including an imidazole compound and aliphatic dicarboxylic acid dihydrazide, to achieve effective curing at lower temperatures (130°C to 165°C).

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If conventional single latent curing agent systems are used, then curing temperature is high (170-180°C), but energy consumption increases and environmental friendliness decreases

Engineering Contradiction:
Improvecuring temperatureVSAvoidenergy consumption
Core Design Contradiction:
TemperatureVSUse of energy by moving object

Solution Approach 1:

The single latent curing agent is segmented into multiple latent curing agents with different activation characteristics. This allows the curing process to occur in stages at lower temperatures, reducing energy consumption while maintaining effective adhesion.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The curing temperature parameter is changed from conventional high temperatures (170-180°C) to lower temperatures (130-165°C) by modifying the curing agent system. This parameter change is achieved through selecting latent curing agents with appropriate activation energies for low-temperature curing.

Inventive Principle:
Principle #35Parameter changes

2Use of energy by moving object

If curing temperature is reduced to 130-165°C, then energy consumption decreases, but maintaining adhesive properties like shear strength and elongation becomes difficult

Engineering Contradiction:
Improveenergy consumptionVSAvoidshear strength and elongation
Core Design Contradiction:
Use of energy by moving objectVSStrength

Solution Approach 1:

The adhesive composition uses a composite system combining epoxy resin with multiple latent curing agents. This composite approach allows the material to achieve both low-temperature curability and high mechanical performance, as each component contributes different properties that complement each other.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent copies successful curing mechanisms from high-temperature systems but adapts them for low-temperature operation by selecting latent curing agents that activate at lower temperatures while producing similar crosslinked network structures that provide mechanical strength.

Inventive Principle:
Principle #26Copying

3Reliability

If conventional adhesive formulations are used, then adhesion to oil surfaces is achieved, but curing requires high temperatures that are not environmentally friendly

Engineering Contradiction:
Improveadhesion to oil surfaceVSAvoidenvironmental harm from high temperature curing
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The curing temperature parameter is fundamentally changed from high to low range, eliminating the need for energy-intensive high-temperature furnaces while maintaining adhesion performance. This reduces environmental harm associated with high-temperature industrial processes.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition ensures excellent adhesion, storage stability, and balanced physical properties, including shear strength and elongation, while reducing energy consumption and environmental impact by allowing curing at lower temperatures.

Implementation Method 1

an adhesive for motor vehicles comprising a curable composition comprising: an elastomer (A), an epoxy resin (B), a latent curing agent (C)

Methodology Applied
Scientific EffectChemical bonding: Chemical Bonding

Implementation Method 2

a crosslinking agent (F) for elastomers

Methodology Applied
Scientific EffectCrosslinking:

Implementation Method 3

an elastomer (A)

Methodology Applied
Scientific EffectElasticity: Elasticity

Implementation Method 4

a thermoplastic resin (E)

Methodology Applied
Scientific EffectPhase change: Phase Change

Data Source

PatentEP4095196B1Curable composition and method for producing curable composition
Publication Date: 2024.08.14 SUNSTAR GIKEN KK
  • EP4095196B1 patent drawing
  • EP4095196B1 patent drawing
  • EP4095196B1 patent drawing

AI summary

Disclosed is a curable composition comprising an elastomer (A), an epoxy resin (B) and a latent curing agent (C), wherein the latent curing agent (C) comprises a combination of two or more latent curing agents.