Colored Curable Composition for Color Filter Pigment Dispersion

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Solution Overview

Problem

Current pigment dispersion systems for color filters in liquid crystal display devices and solid-state image pickup devices face challenges with coarse particles causing uneven color and decreased light transmittance, leading to reduced contrast and curing sensitivity, while dyes offer inferior light resistance and stability.

Innovation Solution

A colored curable composition comprising a complex with a dipyrromethene compound, a phthalocyanine pigment, a dispersing agent, a polymerizable compound, a photopolymerization initiator, and an organic solvent, which improves particle dispersion and stability, enhancing light resistance and contrast.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a pigment dispersion system is used for color filter preparation, then light resistance and stability are improved, but coarse particles cause uneven color and decreased light transmittance

Engineering Contradiction:
Improvelight resistanceVSAvoidcolor uniformity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent changes the particle size parameter of the pigment from conventional coarse particles to ultra-fine particles with average particle sizes of 0.1 to 1.0 μm. This parameter change resolves the contradiction by maintaining the light resistance of pigments while eliminating the coarse particle effects that cause color unevenness and reduced light transmittance.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by combining ultra-fine pigments with specific photosensitive composition matrices. The composite structure allows the pigment particles to be uniformly distributed at ultra-fine scales within the photosensitive material, achieving both the light resistance of pigments and the color uniformity required for high-definition displays.

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If pigment particle size is reduced to improve contrast and light transmittance, then color uniformity is improved, but curing sensitivity during pattern exposing is decreased

Engineering Contradiction:
Improvecolor uniformityVSAvoidcuring sensitivity
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent optimizes the particle size parameter to a specific range of 0.1 to 1.0 μm, which is large enough to maintain good light scattering properties for contrast but small enough to ensure uniform color distribution. This optimized parameter range simultaneously improves color uniformity while maintaining adequate curing sensitivity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent develops composite photosensitive compositions that incorporate ultra-fine pigments with enhanced photosensitive matrices. The composite material design compensates for the reduced curing sensitivity of ultra-fine particles by improving the overall photosensitivity of the composition, enabling both high color uniformity and efficient pattern exposing.

Inventive Principle:
Principle #40Composite materials

3Manufacturing precision

If dyes are used instead of pigments to achieve finer particle size, then color uniformity and light transmittance are improved, but light resistance and stability deteriorate

Engineering Contradiction:
Improvecolor uniformityVSAvoidlight resistance
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent uses composite materials by combining ultra-fine pigments with specific photosensitive composition matrices. The composite structure allows the pigment particles to be uniformly distributed at ultra-fine scales within the photosensitive material, achieving both the light resistance of pigments and the color uniformity required for high-definition displays.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the particle size parameter of the pigment from conventional coarse particles to ultra-fine particles with average particle sizes of 0.1 to 1.0 μm. This parameter change resolves the contradiction by maintaining the light resistance of pigments while eliminating the coarse particle effects that cause color unevenness and reduced light transmittance.

Inventive Principle:
Principle #35Parameter changes

4Reliability

If conventional pigment dispersion is used, then light resistance is maintained, but coarse particles cause decreased contrast and resolution

Engineering Contradiction:
Improvelight resistanceVSAvoidresolution
Core Design Contradiction:
ReliabilityVSMeasurement precision

Solution Approach 1:

The patent applies parameter changes by reducing the pigment particle size to the ultra-fine range of 0.1 to 1.0 μm. This dramatic reduction in particle size eliminates the scattering and absorption effects of coarse particles, thereby improving contrast and enabling high-resolution patterning while preserving the inherent light resistance of pigment-based systems.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves improved light resistance, stability, and contrast by effectively dispersing pigments, reducing particle size, and maintaining high definition, suitable for fine patterns in color filters.

Implementation Method 1

a photopolymerization initiator

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Data Source

PatentUS8354208B2Colored curable composition, method for producing color filter, color filter, solid-state image pickup device, and liquid crystal display device
Publication Date: 2013.01.15 FUJIFILM CORP
  • US8354208B2 patent drawing
  • US8354208B2 patent drawing
  • US8354208B2 patent drawing

AI summary

A colored curable composition including at least (A-1) a complex including a compound represented by the following formula (I) and a metal atom or a metal compound, (A-2) a phthalocyanine pigment, (B) a dispersing agent, (C) a polymerizable compound, (D) a photopolymerization initiator, and (E) an organic solvent:wherein R1 to R6 each independently represent a hydrogen atom or a substituent, but R1 and R6 do not bond to each other to form a ring structure; and R7 represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group or a heterocyclic group.