Curable Composition for Waterproof Coating with Moisture Permeability

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Solution Overview

Problem

Conventional liquid waterproof coating materials lack sufficient moisture permeability and are not effective at low temperatures, leading to issues such as reduced workability and increased risk of cracking due to low elasticity, which compromises their waterproofing performance over time.

Innovation Solution

A curable composition incorporating reactive silyl group-containing organic polymers with oxyethylene units is developed, enhancing water vapor permeability and maintaining waterproofness, even at low temperatures, by forming a siloxane bond through hydrolysis, which allows for improved elasticity and durability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a waterproof sheet is used to provide waterproofness, then water protection is improved, but moisture permeability deteriorates

Engineering Contradiction:
ImprovewaterproofnessVSAvoidmoisture permeability
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The invention changes the physical and chemical parameters of the waterproofing material by using a liquid coating composition that forms a flexible membrane with specific porosity and elasticity characteristics, allowing moisture vapor to pass through while blocking liquid water

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses a composite coating system comprising organic polymers with reactive silyl groups that form a cross-linked network structure, combining waterproofing, moisture permeability, and flexibility properties in a single integrated material

Inventive Principle:
Principle #40Composite materials

2Reliability

If adhesive-backed waterproof tapes are used to seal openings, then waterproofness is improved, but moisture permeability deteriorates

Engineering Contradiction:
ImprovewaterproofnessVSAvoidmoisture permeability
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The invention merges the sealing and waterproofing functions into a single liquid coating application that can be continuously applied around openings and joints, eliminating the need for separate adhesive tapes and maintaining moisture permeability throughout the sealed areas

Inventive Principle:
Principle #5Merging (Combining)

3Ease of operation

If latex polymer is used in liquid waterproof coating material, then ease of application is improved, but workability at low temperature deteriorates

Engineering Contradiction:
Improveease of applicationVSAvoidworkability at low temperature
Core Design Contradiction:
Ease of operationVSProductivity

Solution Approach 1:

The invention changes the chemical composition parameters by replacing latex polymer with organic polymers containing reactive silyl groups, which maintain low-temperature workability and flexibility while preserving ease of application through liquid formulation

Inventive Principle:
Principle #35Parameter changes

4Ease of operation

If latex polymer coating film is used, then ease of application is improved, but elasticity deteriorates

Engineering Contradiction:
Improveease of applicationVSAvoidelasticity
Core Design Contradiction:
Ease of operationVSStrength

Solution Approach 1:

The invention creates a composite cross-linked polymer network through reactive silyl group-containing organic polymers that provide high elasticity and flexibility, enabling the coating film to accommodate substrate movement without cracking while maintaining ease of application in liquid form

Inventive Principle:
Principle #40Composite materials

5Stability of the object's composition

If conventional liquid waterproof coating material is used, then continuous coating formation is improved, but moisture permeability deteriorates

Engineering Contradiction:
Improvecontinuous coating formationVSAvoidmoisture permeability
Core Design Contradiction:
Stability of the object's compositionVSObject-generated harmful factors

Solution Approach 1:

The invention develops a composite coating material where organic polymers with reactive silyl groups form a continuous cross-linked network that inherently provides both waterproofness and moisture permeability, eliminating the trade-off between continuous coating formation and moisture vapor transmission

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention optimizes the molecular weight, functional group content, and cross-linking density parameters of the organic polymer system to achieve a coating film with controlled porosity that allows moisture vapor diffusion while maintaining continuous waterproof coverage

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution significantly increases energy efficiency and durability of buildings while preventing indoor air contamination by maintaining moisture permeability and waterproofness, even in challenging environmental conditions.

Implementation Method 1

organic polymers containing at least one reactive silyl group per molecule are known to be cross-linked by siloxane bond formation involving reactions such as hydrolysis of the reactive silyl group due to moisture

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Implementation Method 2

cross-linked by siloxane bond formation involving reactions such as hydrolysis of the reactive silyl group

Methodology Applied
Scientific EffectSiloxane bond formation: Chemical Bonding

Implementation Method 3

a waterproof sheet having both waterproofness and moisture permeability has been developed... enables to prevent entry of water from the outside as well as to release the water accumulated inside to the outside as water vapor

Methodology Applied
Scientific EffectPermeation: Permeation

Data Source

PatentEP2643386B1Curable composition
Publication Date: 2022.02.23 KANEKA CORP
  • EP2643386B1 patent drawing
  • EP2643386B1 patent drawing
  • EP2643386B1 patent drawing

AI summary

Provided is a curable composition having excellent water vapor permeability, which enables to protect a building from rainwater or moisture in the air and release the water accumulated on the side of the base of the building, to the outside. Also provided is a curable composition which has easy workability and is less likely to allow migration or exudation of a plasticizer to the surface of the cured product. Also provided is a liquid waterproof coating material having moisture permeability which contains the curable composition. The curable composition includes an organic polymer (I) that has less than one hydrolyzable silyl group per molecule on average and contains 5 to 80 wt% of oxyethylene units.