Curable Ink Composition for Large-Area OLED Thin Films

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Solution Overview

Problem

Existing organic light-emitting device manufacturing methods face challenges such as material loss and difficulty in producing large-area devices due to the deposition process, necessitating the development of a solution-based process.

Innovation Solution

An ink composition comprising a specific compound, first and second solvents, which forms a stable thin film through curing, enabling large-area device production with improved efficiency and flatness.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a deposition process is used to manufacture organic light emitting devices, then the device structure can be formed, but material loss occurs frequently and it is difficult to manufacture large-area devices

Engineering Contradiction:
Improvedevice structure formationVSAvoidmaterial loss
Core Design Contradiction:
Manufacturing precisionVSLoss of substance

Solution Approach 1:

The patent employs a solution process using ink composition that can be applied through printing or coating methods, replacing the traditional vacuum deposition process. This allows the organic material layer to be formed by depositing liquid ink composition that is then cured to form the functional layer, eliminating material loss associated with vapor deposition while enabling large-area manufacturing.

Inventive Principle:
Principle #29Pneumatics and hydraulics

Solution Approach 2:

The patent changes the physical state of the organic material from vapor phase (deposition) to liquid solution phase (ink composition). By formulating the organic material as a solution with specific solvents and curable groups, the manufacturing process transitions from vacuum deposition to solution-based printing/coating, resolving both material loss and large-area manufacturing limitations.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If a deposition process is used to manufacture organic light emitting devices, then the device structure can be formed, but it is difficult to manufacture large-area devices

Engineering Contradiction:
Improvedevice structure formationVSAvoiddevice area
Core Design Contradiction:
Manufacturing precisionVSArea of stationary object

Solution Approach 1:

The solution process using liquid ink composition enables printing and coating methods to be used, which can easily cover large areas. The ink composition can be applied uniformly over large substrates through conventional printing or coating equipment, removing the area limitations of vacuum deposition processes.

Inventive Principle:
Principle #29Pneumatics and hydraulics

Solution Approach 2:

By transitioning from vapor phase deposition to liquid solution application, the patent enables large-area manufacturing. The liquid ink composition can be spread uniformly over large areas using printing or coating techniques, allowing fabrication of large-area organic light emitting devices that were not feasible with deposition processes.

Inventive Principle:
Principle #35Parameter changes

3Area of stationary object

If a solution process is used instead of deposition, then large-area devices can be manufactured, but the organic material layer must be stable against subsequent solution processes

Engineering Contradiction:
Improvedevice areaVSAvoidorganic material layer stability
Core Design Contradiction:
Area of stationary objectVSStability of the object's composition

Solution Approach 1:

The patent incorporates curable groups in the organic material structure that enable the material to be cured after deposition. This preliminary curing action creates a stable, cross-linked organic material layer that resists subsequent solution processes, allowing multi-layer fabrication where later layers are deposited in solution without dissolving previously formed layers.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent designs the organic material as a composite structure containing curable functional groups integrated into the molecular structure. This composite design provides both the desired optical/electrical properties and enhanced stability against solvents, as the curable groups form cross-linked networks that prevent solvent penetration and material dissolution during subsequent processing.

Inventive Principle:
Principle #40Composite materials

4Stability of the object's composition

If curable groups are incorporated in the organic material, then stable thin films can be formed through curing, but the material structure becomes more complex

Engineering Contradiction:
Improvethin film stabilityVSAvoidmaterial structure complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The patent introduces curable groups at specific local positions within the organic material structure rather than throughout the entire molecule. This localized modification allows the material to maintain its fundamental optical and electrical properties while gaining curing capability, minimizing structural complexity increase while achieving stable thin film formation through targeted functional group incorporation.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink composition allows for stable thin film formation, low driving voltage, excellent efficiency, and extended service life, with improved flatness and resistance to solvents, facilitating large-area device manufacturing.

Implementation Method 1

the compound includes two or more curable groups, and thus includes a structure which may be polymerized or crosslinked

Methodology Applied
Scientific EffectCuring (polymerization/crosslinking): Photopolymerisation

Implementation Method 2

forming a stable thin film that is not damaged by subsequent solution processes by forming thin films cured by a heat treatment or a light treatment

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS20250311537A1Ink Composition, Organic Material Layer Comprising Same, and Organic Light-emitting Device Comprising Same
Publication Date: 2025.10.02 LG CHEM LTD
  • US20250311537A1 patent drawing
  • US20250311537A1 patent drawing
  • US20250311537A1 patent drawing

AI summary

Provided are an ink composition, an organic material layer including the same and an organic light emitting device including the same, and the ink composition comprises a compound represented by Chemical Formula 1; a first solvent represented by Chemical Formula A; and a second solvent represented by Chemical Formula A and different from the first solvent, wherein Chemical Formula 1 and Chemical Formula A are described herein.