Curable Inkjet Films for OLED Encapsulation

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Solution Overview

Problem

Organic light-emitting diode (OLED) devices are susceptible to degradation by water and oxygen, requiring effective encapsulation methods to maintain stability and reliability, and existing deposition techniques often involve vacuum processing and mask alignment challenges.

Innovation Solution

The use of curable ink compositions deposited via inkjet printing to form a polymeric film as part of a multilayered encapsulation stack, which includes inorganic barrier layers, providing protection and improving light extraction and thermal dissipation, while eliminating the need for vacuum processing and mask alignment.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If vacuum processing operations are used for deposition, then film quality and uniformity are improved, but device complexity and processing time increase

Engineering Contradiction:
Improvefilm uniformityVSAvoidprocessing complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent replaces vacuum-based physical vapor deposition with inkjet printing technology that operates at atmospheric pressure. The inkjet printing system uses precisely controlled droplet deposition to form organic thin films, eliminating the need for vacuum chambers and complex vacuum pumping systems while achieving comparable film uniformity and quality

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The invention changes the operating pressure parameter from vacuum conditions to atmospheric pressure, enabling deposition without vacuum processing equipment. The inkjet printing process controls film formation through precise droplet placement and curing parameters rather than vacuum conditions

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If mask alignment techniques are used for patterning, then patterning precision is improved, but device complexity and processing time increase

Engineering Contradiction:
Improvepatterning precisionVSAvoidalignment complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent replaces mechanical mask alignment systems with digital patterning control through inkjet printing. The inkjet system uses computer-controlled droplet placement to achieve precise patterns without physical masks, eliminating alignment complexity while maintaining or improving patterning precision

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The invention uses digital pattern data to directly control inkjet droplet placement, creating a digital copy or representation of the desired pattern that is transferred to the substrate through programmed deposition, eliminating the need for physical mask copies and alignment procedures

Inventive Principle:
Principle #26Copying

3Area of stationary object

If blanket coating methods are used for deposition, then coverage is improved, but material waste increases

Engineering Contradiction:
Improvecoverage areaVSAvoidmaterial waste
Core Design Contradiction:
Area of stationary objectVSLoss of substance

Solution Approach 1:

The patent applies material only where needed through inkjet printing, depositing organic thin films selectively in specific patterns and locations rather than blanket coating entire substrates. This localized deposition approach achieves complete coverage of required areas while minimizing material waste

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The invention uses partial deposition action by applying material only to the extent necessary for the active region and required coverage areas, avoiding excessive material application and subsequent waste that occurs with blanket coating methods

Inventive Principle:
Principle #16Partial or excessive action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively prevents degradation of OLED devices by forming stable, flexible polymeric films that enhance the mechanical and sealing properties of OLEDs, reducing material waste and processing complexity, and ensuring long-term stability and functionality.

Implementation Method 1

inkjet deposition can be used for the deposition of an organic thin film composition on a substrate

Methodology Applied
Scientific EffectInkjet deposition:

Implementation Method 2

followed by a curing process to form an organic layer on a substrate

Methodology Applied
Scientific EffectCuring: Photopolymerisation

Data Source

PatentUS20240081096A1Curable compositions and techniques for forming organic thin films
Publication Date: 2024.03.07 KATEEVA INC
  • US20240081096A1 patent drawing
  • US20240081096A1 patent drawing
  • US20240081096A1 patent drawing

AI summary

The present teachings relate to various embodiments of a curable ink composition, which once printed and cured form high glass transition temperature polymeric films on a substrate such as, but not limited by, an OLED device substrate. Various embodiments of the curable ink compositions comprise di(meth)acrylate monomers, as well as multifunctional crosslinking agents.