Radiation-Curable Inkjet Ink for Stable Pigment Dispersion

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Solution Overview

Problem

Existing actinic radiation-curable inkjet inks, particularly yellow inks, suffer from low dispersion stability and weather resistance due to interactions between pigments and gelling agents, leading to image quality deterioration and coalescence of ink droplets during high-speed printing.

Innovation Solution

An actinic radiation-curable inkjet ink formulation containing a photopolymerizable compound, photoinitiator, gelling agent, pigment, dispersion aid, and pigment-dispersing agent, where the dispersion aid and pigment share a specific structural bond, enhancing dispersion stability and preventing interaction with the gelling agent, thereby improving image quality and weather resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If a gelling agent is added to enhance pinning property and suppress ink droplet coalescence, then image quality improves, but pigment dispersion stability deteriorates due to interaction between pigment and gelling agent

Engineering Contradiction:
Improveimage qualityVSAvoidpigment dispersion stability
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

The patent introduces a specific dispersing agent as an intermediary substance between the pigment and gelling agent. This dispersing agent has a specific molecular structure that preferentially binds to the pigment particles, creating a protective barrier that prevents the pigment from interacting with the gelling agent. The dispersing agent thus mediates the relationship between pigment and gelling agent, allowing the gelling agent to provide pinning properties while the dispersing agent maintains pigment dispersion stability.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If high-speed recording is performed with densely dropped ink droplets, then productivity increases, but adjacent dots coalesce and image quality deteriorates

Engineering Contradiction:
Improverecording speedVSAvoidimage quality
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent utilizes the phase transition property of the gelling agent, which transitions from a liquid state during ink ejection to a gel state after deposition on the substrate. This phase transition occurs rapidly after the ink droplet is ejected, causing the deposited ink to solidify and maintain its shape. This allows densely packed ink droplets to be ejected at high speed without coalescing, as each droplet rapidly gels upon contact with the substrate, preserving image quality while enabling high-speed recording.

Inventive Principle:
Principle #36Phase transitions

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink achieves high dispersion stability and weather resistance, enabling high-definition and durable printed products with reduced ink droplet coalescence.

Implementation Method 1

irradiating the ink droplet having landed on the recording medium with an active ray to cure the ink droplet

Methodology Applied
Scientific EffectPhotopolymerisation: Photopolymerisation

Implementation Method 2

adding a gelling agent to an ink to cause a sol-gel phase transition by temperature

Methodology Applied
Scientific EffectSol-gel phase transition: Phase Change

Data Source

PatentEP4656693A1Actinic radiation-curable inkjet ink and method for producing printed product using the same
Publication Date: 2025.12.03 KONICA MINOLTA INC
  • EP4656693A1 patent drawing
  • EP4656693A1 patent drawing
  • EP4656693A1 patent drawing

AI summary

An object of the present invention is to provide an actinic radiation-curable inkjet ink containing a gelling agent and capable of obtaining satisfactory dispersion stability of a pigment and a high weather resistance of an obtained printed product. An actinic radiation-curable inkjet ink that achieves the object is an actinic radiation-curable inkjet ink containing a photopolymerizable compound, a photoinitiator, a gelling agent, a pigment, a dispersion aid, and a pigment-dispersing agent, and the dispersion aid contains a compound having a specific structure, and the pigment contains a compound having a specific structure.