Curable Phase Change Ink Crystalline Polyester Resin Gel State

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Solution Overview

Problem

Phase change inks used in inkjet printing often exhibit microbanding due to uneven ink distribution, which can be exacerbated by contact leveling techniques that cause ink splitting and transfer issues, leading to poor print quality and the need for frequent maintenance of contact members.

Innovation Solution

A curable phase change ink composition incorporating a crystalline polyester resin with specific molecular weight and polydispersity ranges, along with a gellant and curable monomers, that forms a gel state upon cooling, reducing ink splitting and transfer during contact leveling and enhancing print quality.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If contact leveling is applied to phase change ink, then ink distribution uniformity is improved, but ink splitting and transfer occur causing print quality degradation

Engineering Contradiction:
Improveink distribution uniformityVSAvoidink splitting and transfer
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The patent modifies the chemical composition parameters of the phase change ink by incorporating specific polymers (polyester, polyamide, polyurethane) with controlled molecular weights and ratios. This changes the ink's rheological properties to reduce splitting and transfer during contact leveling while maintaining distribution uniformity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite ink formulation combining phase change materials with multiple polymer types (polyester, polyamide, polyurethane) and optional additives. This composite structure provides both the phase change functionality for uniform distribution and the polymer matrix that prevents ink splitting and transfer

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If contact leveling is used to address microbanding, then ink distribution is normalized, but ink accumulates on contact members requiring frequent maintenance

Engineering Contradiction:
Improveink distribution normalizationVSAvoidmaintenance frequency
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The patent adjusts the chemical composition parameters including polymer molecular weight (1,000-1,000,000 Da), polymer to phase change material ratio (1:99 to 99:1), and adds maintenance reduction agents. These parameter changes modify surface tension and adhesion properties to prevent ink accumulation on contact members

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent formulates the ink with specific polymers and additives that create a self-cleaning effect, allowing the contact members to be easily cleaned or replaced less frequently. The ink composition itself helps prevent buildup, extending the operational life of contact members

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Reliability

If phase change ink is used for inkjet printing, then nozzle clogging is eliminated, but microbanding occurs due to uneven ink distribution

Engineering Contradiction:
Improvenozzle clogging preventionVSAvoidink distribution uniformity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent modifies the rheological parameters of the phase change ink by incorporating polymers with specific molecular weights and ratios. This changes the ink's flow characteristics to ensure uniform distribution during jetting while maintaining the solid-phase stability that prevents nozzle clogging

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite formulation where the polymer matrix (polyester, polyamide, polyurethane) provides structural integrity for uniform distribution, while the phase change materials maintain the solid-liquid transition properties that prevent clogging. The combination achieves both reliability and precision

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink composition effectively minimizes ink splitting and transfer during contact leveling, maintaining print quality and reducing the need for frequent contact member maintenance by forming a stable gel state upon cooling, thus addressing microbanding and ink distribution issues.

Implementation Method 1

curable phase change inks... that comprise a curable gellant and a crystalline polyester resin

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 2

forms a gel state upon cooling

Methodology Applied
Scientific EffectGel formation: Gel

Implementation Method 3

radiation-curable phase change inks, such as ultraviolet-light-curable phase change inks

Methodology Applied
Scientific EffectPhotopolymerisation: Photopolymerisation

Data Source

PatentUS8657430B2Curable phase change inks containing crystalline polyesters
Publication Date: 2014.02.25 GENESEE VALLEY INNOVATIONS LLC
  • US8657430B2 patent drawing
  • US8657430B2 patent drawing
  • US8657430B2 patent drawing

AI summary

This disclosure is generally directed to curable phase change inks, such as radiation-curable phase change inks, and their use in forming images, such as through inkjet printing. More specifically, this disclosure is directed to radiation-curable phase change inks, such as ultraviolet-light-curable phase change inks, that an ink vehicle and at least one crystalline polyester resin.