Curable Silicone Composition for Flexible OLED Encapsulation

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Current encapsulation technologies for flexible organic electronic devices are inadequate due to their inability to provide effective moisture and oxygen barrier properties, leading to premature deterioration and limited flexibility, which restricts the widespread commercialization of devices like OLEDs and OPVs.

Innovation Solution

A curable silicone composition comprising organopolysiloxane with specific organofunctional groups, cross-linkers, and reaction accelerating agents is developed, offering high refractive index, optical clarity, flexibility, and improved barrier properties suitable for large-area, scalable encapsulation of organic electroluminescent display devices.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If glass encapsulation is used to provide moisture and oxygen barrier properties, then barrier performance is improved, but device flexibility deteriorates

Engineering Contradiction:
Improvemoisture and oxygen barrier propertiesVSAvoiddevice flexibility
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent employs flexible thin film encapsulation layers comprising alternating inorganic barrier layers and organic buffer layers. The inorganic layers provide moisture and oxygen barrier properties, while the organic layers provide flexibility and stress relief, resolving the contradiction between barrier performance and device flexibility.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The encapsulation structure uses composite materials combining inorganic substances (such as silicon oxide, silicon nitride) for barrier properties with organic substances (such as polymers) for flexibility. This composite approach allows simultaneous achievement of both moisture/oxygen barrier performance and device flexibility.

Inventive Principle:
Principle #40Composite materials

2Reliability

If multilayer thin film encapsulation is used to provide barrier properties, then moisture and oxygen transmission is reduced, but manufacturing complexity increases

Engineering Contradiction:
Improvebarrier propertiesVSAvoidmanufacturing complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The encapsulation system is segmented into multiple thin alternating layers of inorganic and organic materials. Each layer is relatively thin and serves a specific function, allowing the complex barrier function to be achieved through simple repetitive deposition processes rather than requiring complex monolithic structures.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

By using thin film technology with alternating inorganic and organic layers, the patent achieves effective barrier properties through multiple thin layers that can be deposited using standard semiconductor manufacturing techniques, reducing manufacturing complexity compared to thicker or more complex encapsulation structures.

Inventive Principle:
Principle #30Flexible shells and thin films

3Reliability

If glass encapsulation with epoxy glue is used, then barrier performance is improved, but cost and processing difficulty increase

Engineering Contradiction:
Improvebarrier performanceVSAvoidprocessing ease and cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The thin film encapsulation structure can be directly deposited onto the substrate using vapor deposition techniques, eliminating the need for separate glass lids and epoxy glue application processes. This integration simplifies manufacturing steps, reduces material costs, and improves processing ease while maintaining barrier performance.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The patent merges the encapsulation function directly into the device structure through thin film deposition, combining what were previously separate components (glass lid, epoxy adhesive, barrier layer) into an integrated thin film encapsulation system, thereby reducing manufacturing steps and cost.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The curable silicone composition extends the lifetime of organic electroluminescent display devices by providing a flexible, high-quality barrier that is both easy to process and scalable, while maintaining excellent optical clarity and thermal resistivity.

Implementation Method 1

a curable silicone composition comprising an organopolysiloxane. The organopolysiloxane comprises organofunctional groups in the main chain of the polysiloxane

Methodology Applied
Scientific EffectCross-linking reaction: Chemical Bonding

Implementation Method 2

Cured materials formed from compositions comprising such organopolysiloxanes have been found to exhibit relatively high refractive index, good optical clarity, flexibility, thermal resistivity, crack resistivity, and/or moisture permeability

Methodology Applied
Scientific EffectPermeation barrier: Permeation

Data Source

PatentUS10287400B2Curable silicone composition and applications and uses thereof
Publication Date: 2019.05.14 MOMENTIVE PERFORMANCE MATERIALS INC
  • US10287400B2 patent drawing
  • US10287400B2 patent drawing
  • US10287400B2 patent drawing

AI summary

A curable composition comprising (a) an organopolysiloxane comprising a curable functional group; (b) a cross-linker comprising a silyl hydride group or a thiol group; (c) a reaction accelerator; (d) optionally an inhibitor; and (e) optionally other additives. The curable composition exhibits high refractive index and optical clarity. The curable composition can be used to prepare a cured material that exhibits high refractive index, optical clarity, crack resistance, and low moisture vapor permeability.