Curable Thermal Ink Composition for Smear-Resistant Printing

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Solution Overview

Problem

Conventional thermally-ejectable printing fluids are non-curable and prone to smearing and color running, requiring expensive piezoelectric printheads and involving organic solvents that need special handling and disposal, while curable fluids are not suitable for thermal ejection systems.

Innovation Solution

A curable, thermally ejectable printing fluid composition comprising a curable liquid-phase monomer, a non-aqueous volatile driver fluid, an initiator, and a phosphate ester resistor protectant, designed for use with thermal fluid ejection devices, allowing for rapid curing and integration into thermal printheads, reducing maintenance and solvent usage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If conventional thermally-ejectable printing fluids are used, then the printing device can operate with simple thermal printheads, but the fluids are non-curable and prone to smearing and color running

Engineering Contradiction:
Improveprinthead simplicityVSAvoidprint quality
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent changes the chemical parameters of the printing fluid by formulating a curable composition containing monomers, oligomers, and photoinitiators that can undergo polymerization. This allows the fluid to be ejected thermally like conventional fluids but then cured to achieve durable, smear-resistant printing, thus improving print quality while maintaining thermal printhead simplicity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite printing fluid system combining curable polymer components (monomers and oligomers) with photoinitiators and conventional ink additives. This composite formulation enables both thermal ejection compatibility and subsequent curing capability, resolving the contradiction between simple printhead operation and high-quality durable printing

Inventive Principle:
Principle #40Composite materials

2Reliability

If curable printing fluids are used to achieve fast drying times, then smearing is reduced, but the fluids may not be printable via thermal ejection and require expensive piezoelectric printheads

Engineering Contradiction:
Improvedrying speedVSAvoidprinthead type
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent modifies the physical parameters of curable fluids by adjusting viscosity, surface tension, and boiling point through careful selection of monomer and oligomer combinations. These parameter adjustments enable the curable fluid to be compatible with thermal ejection mechanisms, eliminating the need for expensive piezoelectric printheads while maintaining fast drying capabilities

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent makes curable printing fluid compatible with disposable or replaceable thermal printheads rather than requiring expensive permanent piezoelectric units. This allows the system to use cheaper thermal printhead technology while still achieving the fast drying and durable printing benefits of curable fluids

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Reliability

If curable printing fluids with organic solvents are used, then curability is achieved, but additional equipment and care are needed for safe evaporation and disposal

Engineering Contradiction:
Improvecuring capabilityVSAvoidsolvent handling equipment
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent replaces hazardous organic solvents with an aqueous-based inert environment formulation. The curable components are suspended or dissolved in water rather than volatile organic solvents, eliminating the need for special evaporation equipment and disposal systems while maintaining curing capability through photoinitiation

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Solution Approach 2:

The patent extracts and removes hazardous organic solvent components from the printing fluid formulation, retaining only the essential curable components (monomers, oligomers, photoinitiators) in an aqueous base. This extraction eliminates the need for special solvent handling equipment while preserving the curable properties needed for durable printing

Inventive Principle:
Principle #2Taking out (Extraction)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables fast, durable printing on various substrates with reduced smearing and solvent outgassing, lowering printhead maintenance and costs by using thermal printheads, which are more cost-effective and suitable for high-speed applications.

Implementation Method 1

a substantially nonaqueous volatile driver fluid capable of being vaporized by a thermal fluid ejection printhead

Methodology Applied
Scientific EffectVaporization: Evaporation

Implementation Method 2

a curable liquid-phase monomer... an initiator

Methodology Applied
Scientific EffectPolymerization: Photopolymerisation

Data Source

PatentUS7956097B2Curable thermally ejectable printing fluid
Publication Date: 2011.06.07 MATTHEWS INTERNATIONAL CORP

AI summary

Various embodiments related to curable printing fluids are disclosed. One example embodiment provides a curable printing fluid composition for a thermal fluid ejection device, the composition comprising a curable liquid-phase monomer, a substantially nonaqueous volatile driver fluid capable of being vaporized by a thermal fluid ejection printhead, an initiator, a phosphate ester resistor protectant, and a colorant comprising a dye.