Curcumin-Derivative Resist Underlayer Composition for Wet Etch Removal

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Solution Overview

Problem

The existing resist underlayer films in semiconductor manufacturing processes, particularly in the FOWLP process, lack sufficient solubility in wet etching chemical liquids and are not easily removable without causing damage to the processed substrate.

Innovation Solution

A resist underlayer film-forming composition containing a curcumin derivative, which exhibits excellent solubility in wet etching chemical liquids and resistance to resist solvents or developers, is developed.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a resist underlayer film is designed to have excellent resistance to resist solvents and developers, then the film maintains structural integrity during lithography processes, but the film becomes difficult to remove and requires dry etching which increases process complexity and cost

Engineering Contradiction:
Improveresistance to resist solvent and developerVSAvoidremovability of resist underlayer film
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent applies parameter changes by modifying the chemical composition parameters of the resist underlayer film through the use of curcumin derivatives with specific molecular structures (Formula 1). These structural parameters enable the film to exhibit dual characteristics: high resistance to organic solvents and alkaline developers during lithography, while simultaneously maintaining high solubility in wet etching chemical liquids for easy removal. This resolves the contradiction by changing the chemical composition parameters to achieve both durability during processing and ease of removal afterward.

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If dry etching is used to remove the resist underlayer film, then complete removal is achieved, but the process cost increases and process simplification is hindered

Engineering Contradiction:
Improvecomplete removal of resist underlayer filmVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent applies mechanics substitution by replacing the mechanical/physical dry etching process with a chemical wet etching process. The curcumin derivative-based resist underlayer film is specifically designed to be highly soluble in wet etching chemical liquids, allowing complete removal through chemical dissolution rather than physical sputtering. This substitution simplifies the manufacturing process while achieving complete film removal, thereby reducing both process complexity and cost.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Device complexity

If wet etching chemical liquid is used to remove the resist underlayer film, then process simplification is achieved, but the substrate may be damaged due to insufficient film selectivity

Engineering Contradiction:
Improveprocess simplicityVSAvoidsubstrate damage
Core Design Contradiction:
Device complexityVSObject-affected harmful factors

Solution Approach 1:

The patent applies local quality by designing the resist underlayer film with spatially differentiated chemical properties. The curcumin derivative structure provides high solubility in wet etching chemical liquids at the film level, while the film itself acts as a protective layer during lithography. This localized chemical property enhancement ensures that the wet etching process selectively removes only the resist underlayer film without damaging the underlying substrate, achieving both process simplification and substrate protection.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition allows for easy removal of the resist underlayer film without damaging the substrate, reducing process costs and simplifying the manufacturing process.

Implementation Method 1

a film obtained using a resist underlayer film-forming composition containing a curcumin derivative exhibits excellent removability (solubility) in a wet etching chemical liquid

Methodology Applied
Scientific EffectSolvation: Solvation

Implementation Method 2

exhibits excellent resistance to a resist solvent, which is an organic solvent, or a resist developer, which is an alkaline aqueous solution

Methodology Applied
Scientific EffectSelective solubility: Solvation

Data Source

PatentEP4621487A1Resist underlayer film-forming composition containing curcumin derivative
Publication Date: 2025.09.24 NISSAN CHEM CORP
  • EP4621487A1 patent drawing
  • EP4621487A1 patent drawing
  • EP4621487A1 patent drawing

AI summary

Provided is a resist underlayer film that exhibits excellent removability (solubility) in a wet etching chemical liquid while mainly exhibiting excellent resistance to a resist solvent, which is an organic solvent, or a resist developer, which is an alkaline aqueous solution. A resist underlayer film-forming composition contains at least any one of a compound having a partial structure represented by Formula (1) or a polymer having a partial structure represented by Formula (1), and a solvent. (In formula (1), each -X- independently represents -O-, -S-, -NH-, -C(=O)O-, or -C(=O)-; each -Y- independently represents -CH2CH(OH)-, -C(=O)-, -O-, or -S-; A represents an alkyl group, a hydroxy group, a halogen atom, or an alkoxy group; n1 satisfies 1 ≤ n1 ≤ 5, m1 satisfies 0 ≤ m1 ≤ 4, and n1 and m1 satisfy n1 + m1 ≤ 5; n2 satisfies 1 ≤ n2 ≤ 5, m2 satisfies 0 ≤ m2 ≤ 4, and n2 and m2 satisfy n2 + m2 ≤ 5; and * represents a bond.)