Cu-Sn-Bi Sliding Material with Nonuniform Bismuth Distribution

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Solution Overview

Problem

Existing Cu-based sliding materials face challenges in recycling due to the presence of lead, which is environmentally hazardous, and require lubricating oil for optimal performance, leading to issues like reduced bonding strength and work hardening during manufacturing.

Innovation Solution

A sliding material with a sintered layer comprising 5-15 mass % elemental Bi nonuniformly distributed in a Cu-Sn alloy matrix, eliminating the need for oil grooves and enhancing bonding strength and lubrication by forming minute depressions for oil accumulation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If lead bronze is used as a Cu-based bearing alloy, then good sliding properties and low cost are achieved, but environmental pollution from lead dissolution occurs

Engineering Contradiction:
Improvesliding propertiesVSAvoidlead pollution
Core Design Contradiction:
Ease of operationVSObject-affected harmful factors

Solution Approach 1:

The patent replaces lead (Pb) with bismuth (Bi) as the lubricating element in the Cu-Sn alloy matrix. This parameter substitution changes the chemical composition while maintaining the functional mechanism where the soft element forms a lubricating film on the sliding surface, providing good sliding properties without lead pollution.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent converts the harmful effect of lead dissolution into a beneficial lead-free composition. By using Bi instead of Pb, the material maintains its self-lubricating capability while eliminating environmental harm, turning a harmful material into a safe alternative with equivalent or superior performance.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Object-affected harmful factors

If Cu-Sn-Bi sliding alloys are used, then lead-free composition is achieved, but insufficient lubricating effect without lubricating oil occurs

Engineering Contradiction:
Improvelead-free compositionVSAvoidlubricating effect
Core Design Contradiction:
Object-affected harmful factorsVSEase of operation

Solution Approach 1:

The patent creates local quality variations by nonuniformly distributing Bi particles in the sintered layer. This results in regions with different Bi concentrations, where some areas provide strong lubrication while others maintain structural integrity, enabling the material to function effectively both with and without external lubricating oil.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent introduces dynamic adaptability by creating a sintered layer that can adjust its lubricating properties based on operating conditions. The nonuniform Bi distribution allows the material to self-regulate lubrication effectiveness, providing sufficient lubricating effect whether lubricating oil is present or absent.

Inventive Principle:
Principle #15Dynamics

3Stability of the object's composition

If Bi is uniformly dispersed in Cu-based matrix, then homogeneous material structure is achieved, but insufficient oil accumulation capability occurs

Engineering Contradiction:
Improvehomogeneous structureVSAvoidoil accumulation
Core Design Contradiction:
Stability of the object's compositionVSQuantity of substance

Solution Approach 1:

The patent deliberately creates nonuniform Bi distribution with local quality variations. Regions with higher Bi concentration provide oil accumulation zones, while other regions maintain structural stability. This local differentiation enables both homogeneous overall composition and sufficient oil accumulation capability.

Inventive Principle:
Principle #3Local quality

4Strength

If sliding parts are made with bearing alloy layer bonded to steel backing plate, then mechanical strength is improved, but recycling difficulty increases

Engineering Contradiction:
Improvemechanical strengthVSAvoidrecycling difficulty
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The patent segments the sliding part into two functional layers: a steel backing plate providing mechanical strength and a Cu-Sn-Bi sintered layer providing sliding properties. This segmentation allows the layers to be manufactured separately and then bonded, facilitating future separation and recycling of each component according to its optimal recycling pathway.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent uses composite material construction with a steel substrate and a copper-based sintered overlay. This composite structure combines the advantages of both materials: the steel provides structural integrity while the copper-based layer provides self-lubricating properties and can be recycled separately from the steel backing plate.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The sliding material exhibits superior sliding properties in both lubricated and dry conditions, with increased bonding strength and reduced wear, outperforming traditional lead-based materials without the need for oil grooves.

Implementation Method 1

the lead spreads as a thin layer on the surface of the opposing member and provides good sliding properties by acting as a lubricating oil

Methodology Applied
Scientific EffectLubrication: Lubrication

Implementation Method 2

Bi performs the same function as Pb in conventional lead bronze, i.e., it forms a thin film covering the surface of the opposing member and acts as a lubricating oil to provide good sliding properties

Methodology Applied
Scientific EffectSolid lubrication:

Implementation Method 3

a first sintering step comprising heating the nonuniform mixed powder and the backing plate to sinter the nonuniform mixed powder to the backing plate

Methodology Applied
Scientific EffectSintering: Sintering

Implementation Method 4

The hard Cu—Sn alloy matrix can support a member being slidably supported by a sliding part (referred to below as 'the opposing member') without wearing

Methodology Applied
Scientific EffectWear resistance: Wear

Implementation Method 5

a sliding part made from a conventional copper-based sliding material in which a Cu—Sn—Bi alloy is bonded to a steel plate does not exhibit a sufficient lubricating effect

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Data Source

PatentUS7906222B2Sliding material and a method for its manufacture
Publication Date: 2011.03.15 SENJU METAL IND CO LTD
  • US7906222B2 patent drawing
  • US7906222B2 patent drawing
  • US7906222B2 patent drawing

AI summary

A sliding material has a sintered layer formed atop a backing plate. The sintered layer contains 5-15 mass % of Bi nonuniformly distributed in a Cu—Sn alloy matrix consisting essentially of 8-12 mass % of Sn and a remainder of Cu. The sliding material can be manufactured by nonuniformly mixing Cu—Sn alloy powder and Bi powder, dispersing the mixed powder on a backing plate, and sintering the mixed powder to form a sintered layer on the backing plate. The sliding material does not undergo seizing and does not have separation of the sintered layer from the backing plate even when used in severe conditions such as in hydraulic equipment or construction equipment.