Multilayer Cutting Tool Coating for Chipping-Resistant Durability

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Solution Overview

Problem

Conventional coated cutting tools with hard coating layers, such as those described in PTLs 1 and 2, lack sufficient durability under high load conditions, particularly against chipping, fracture, and peeling during cutting operations.

Innovation Solution

A surface-coated cutting tool with a hard coating layer comprising a titanium carbonitride inner layer, a titanium nitride lower intermediate layer, a titanium carbonitride upper intermediate layer, a titanium oxycarbonitride bonding auxiliary layer, and an α-aluminum oxide outer layer, where the grain boundaries are continuous and the bonding auxiliary layer has a non-acicular structure, enhancing durability and resistance to chipping.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If a hard coating layer is formed by vapor deposition on the tool substrate, then wear resistance is improved, but durability against abnormal damage (chipping, fracture, peeling) under high load is insufficient

Engineering Contradiction:
Improvewear resistanceVSAvoiddurability against abnormal damage
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The hard coating layer is divided into five distinct functional layers: inner layer (titanium carbonitride), lower intermediate layer (titanium nitride), upper intermediate layer (titanium carbonitride), bonding auxiliary layer (titanium oxycarbonitride), and outer layer (α-aluminum oxide). Each layer serves specific purposes - the inner layer provides wear resistance, the intermediate layers ensure continuous grain boundaries for structural integrity, the bonding auxiliary layer enhances adhesion, and the outer layer provides oxidation resistance and surface protection. This segmentation resolves the contradiction by distributing different protective functions across multiple layers.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The coating structure uses composite materials with different properties in each layer. Titanium carbonitride provides hardness and wear resistance, titanium nitride offers ductility and shock absorption, and α-aluminum oxide provides oxidation resistance. The combination of these materials in a layered composite structure simultaneously achieves wear resistance and durability against abnormal damage under high load conditions.

Inventive Principle:
Principle #40Composite materials

2Strength

If the bonding layer has an acicular structure to improve bonding, then adhesion is enhanced, but durability under high load against cutting edge damage is reduced

Engineering Contradiction:
Improvebonding strengthVSAvoiddurability under high load
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The bonding auxiliary layer uses titanium oxycarbonitride with a specific composition ratio and a thickness of 5-50 nm, which is significantly thinner than conventional bonding layers. The layer is formed with a non-acicular (equiaxed grain) structure through controlled vapor deposition parameters, including specific partial pressures of reactive gases and deposition temperature. These parameter changes maintain adequate bonding while eliminating the acicular structure that causes stress concentration and reduces durability under high load.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The tool exhibits significantly improved durability and resistance to chipping and wear under high load conditions, extending its lifespan and performance in cutting operations.

Implementation Method 1

a hard coating layer formed by vapor deposition on the surface of a tool substrate

Methodology Applied
Scientific EffectVapor deposition: Physical Vapour Deposition

Data Source

PatentEP4129539B1Surface-coated cutting tool
Publication Date: 2024.11.06 MITSUBISHI MATERIALS CORP
  • EP4129539B1 patent drawingFigure 1
  • EP4129539B1 patent drawing
  • EP4129539B1 patent drawing

AI summary

A surface coated cutting tool includes a tool substrate; and a hard coating layer on the tool substrate. The hard coating layer includes, in sequence from the tool substrate toward a surface of the tool, a titanium carbonitride inner layer, a titanium nitride lower intermediate layer, a titanium carbonitride upper intermediate layer, a titanium oxycarbonitride bonding auxiliary layer, and an aluminum oxide outer layer. Titanium nitride grain boundaries in the lower intermediate layer and titanium carbonitride grain boundaries in the upper intermediate layer are continuous from titanium carbonitride grain boundaries in the inner layer. The texture coefficient TC(422) of titanium carbonitride in the inner layer and the upper intermediate layer is 3.0 or more, and the texture coefficient TC(0 0 12) of α-aluminum oxide in the outer layer is 5.0 or more.