CVI Densification of Composite Preforms via Hole Formation

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Solution Overview

Problem

CVI type processes for densifying fibrous substrates often result in densification gradients due to preferential matrix deposition at the surface, leading to inhomogeneous properties and the need for multiple cycles with intermediate peeling to facilitate gas diffusion.

Innovation Solution

Forming holes in the substrates by removing material, such as with a high-pressure water jet or localized thermal action, to create a short path for the reaction gas phase, allowing for almost uniform densification in a single cycle without the need for peeling.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If CVI type processes are used for densifying fibrous substrates, then the substrates can be densified by matrix deposition, but densification gradients occur due to preferential surface deposition

Engineering Contradiction:
Improvedensification uniformityVSAvoidcomposition homogeneity
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

The substrate is segmented into multiple zones based on their densification status. The gas phase is directed to flow through different paths: superficial parts are bypassed while core regions receive enhanced gas phase access through created channels. This segmentation allows simultaneous treatment of different substrate regions with appropriate gas flow distribution, resolving the contradiction between surface deposition efficiency and core densification uniformity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

An intermediary structure (channels or pores) is introduced into the substrate to mediate gas phase transport. These intermediaries provide dedicated pathways for the gas phase to reach core regions without being completely blocked by surface deposition, thus maintaining composition homogeneity while enabling effective densification throughout the substrate volume.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If multiple CVI cycles are performed with intermediate peeling, then densification can be continued after surface porosity reopening, but the process complexity and time increase

Engineering Contradiction:
Improvedensification rateVSAvoidtotal process time
Core Design Contradiction:
ProductivityVSLoss of time

Solution Approach 1:

Channels are created in the substrate before the CVI densification process begins. This preliminary action establishes gas phase pathways in advance, allowing the gas phase to efficiently reach core regions during the densification process without requiring intermediate peeling operations. The result is a single-cycle process that achieves uniform densification, eliminating the time loss associated with multiple cycles and intermediate peeling.

Inventive Principle:
Principle #10Preliminary action

3Manufacturing precision

If holes are formed by needle insertion to provide gas phase access, then diffusion paths are shortened, but fiber damage occurs and densification gradient is not sufficiently minimized

Engineering Contradiction:
Improvedensification uniformityVSAvoidsubstrate integrity
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The mechanical needle insertion process is replaced with a non-contact or gentle material removal process such as water jet machining or localized thermal action. This substitution eliminates fiber damage while still creating the necessary channels for gas phase access. The resulting channels provide sufficient diffusion paths for uniform densification without compromising substrate integrity.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The method of hole formation is changed from mechanical insertion to material removal by water jet or thermal action. This parameter change in the manufacturing process allows channel creation without the damaging mechanical forces of needle insertion, thereby maintaining substrate integrity while achieving the same functional goal of shortened gas phase diffusion paths.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Achieves almost uniform densification of fibrous substrates, reducing the number of densification cycles and eliminating the necessity for intermediate peeling, thereby enhancing the uniformity of composite material properties.

Implementation Method 1

Forming holes in the substrates by removing material, such as with a high-pressure water jet

Methodology Applied
Scientific EffectHigh-pressure water jet: Jet Erosion

Implementation Method 2

Forming holes in the substrates by removing material, such as with a high-pressure water jet or localized thermal action

Methodology Applied
Scientific EffectLocalized thermal action: Laser Ablation

Implementation Method 3

A reaction gas phase is admitted into the oven to deposit the material constituting the matrix within the porosity of the substrates by decomposition of one or more constituents of the gas phase, or reaction between several constituents, under conditions of temperature and pressure determined

Methodology Applied
Scientific EffectChemical vapour infiltration: Chemical Vapour Deposition

Implementation Method 4

The substrate is heated for example by passing an electric current or by electromagnetic coupling with an inductor, the substrate being made of electrically conductive fibers such as carbon fibers

Methodology Applied
Scientific EffectJoule heating: Joule Heating

Implementation Method 5

The substrate is heated for example by passing an electric current or by electromagnetic coupling with an inductor

Methodology Applied
Scientific EffectElectromagnetic induction: Electromagnetic Induction

Data Source

PatentEP1886046B1Method and substrate for making composite material parts by chemical vapour infiltration densification and resulting parts
Publication Date: 2011.04.27 SNECMA PROPULSION SOLIDE
  • EP1886046B1 patent drawingFigure 1~2
  • EP1886046B1 patent drawingFigure 3~6
  • EP1886046B1 patent drawingFigure 7~13

AI summary

The invention concerns a composite material part made by forming a fibrous preform (20), forming holes (22) extending in the preform from at least one side thereof, and densifying the preform with a matrix formed at least partly by a chemical vapour infiltration in gas phase (CVI). The holes (22) are formed by removing the material thereof by rupturing the fibers, for example by high-pressure jet machining, the fiber arrangement in the preform provided with holes being substantially unmodified relative to the original arrangement prior to the formation of the holes. The densification gradient is thus highly reduced, and a density may be obtained in a single densifying cycle which, in prior art, required several cycles separated by intermediate decrusting.