Cyclic CVD Conductive Structure Formation for Defect Reduction

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Solution Overview

Problem

Existing semiconductor manufacturing processes face challenges in reducing defects and improving uniformity as device scaling-down continues, particularly in forming conductive structures on dielectric surfaces.

Innovation Solution

A method involving multiple deposition and modification processes using specific gases (G1, G2, G3, and G4) in a chemical vapor deposition chamber to form and modify conductive structures on dielectric surfaces, with G2 passivating the surfaces of the first conductive structures to prevent defects and G4 forming second conductive structures on the dielectric surface, thereby reducing voids and seams.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional deposition processes are used to form conductive structures, then the manufacturing process is simple, but the conductive structures have high resistance and contain defects such as voids and seams

Engineering Contradiction:
Improvequality of conductive structureVSAvoidcomplexity of deposition process
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The deposition process is segmented into multiple cycles, each consisting of a deposition step followed by a modification step. This segmentation allows the process to build conductive structures incrementally while continuously improving their quality, resolving the contradiction between simple manufacturing and high reliability by breaking down the complex task into manageable, repeating units.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent employs periodic deposition-modification cycles where deposition and modification steps alternate. This periodic action enables the system to repeatedly deposit material and then modify it to reduce defects and resistance, achieving high reliability through iterative improvement rather than a single complex process step.

Inventive Principle:
Principle #19Periodic action

2Productivity

If device scaling-down continues, then device density increases, but defects in conductive structures become more prevalent

Engineering Contradiction:
Improvedevice densityVSAvoiduniformity of conductive structure
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The modification step is performed preliminarily during each deposition cycle, before subsequent deposition steps. This preliminary modification prepares the surface and reduces defects early in the process, ensuring that as devices are scaled down and packed more densely, the conductive structures maintain high uniformity and low defect rates throughout the formation process.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The cyclic deposition-modification process ensures continuous improvement of the conductive structure quality throughout the formation process. Rather than a single continuous deposition that accumulates defects, the continuous alternating action of deposition and modification maintains high manufacturing precision even as device density increases through scaling.

Inventive Principle:
Principle #20Continuity of useful action

3Reliability

If additional adhesion or diffusion barrier layers are added to improve performance, then adhesion and performance improve, but the manufacturing process becomes more complex and time-consuming

Engineering Contradiction:
Improveadhesion and performanceVSAvoidmanufacturing cycle time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent merges the functions of adhesion promotion and diffusion barrier into the conductive structure itself through the modification step. By modifying the surface properties of the deposited conductive material, the process achieves both good adhesion and diffusion barrier performance without requiring separate additional layers, thus reducing manufacturing cycle time while maintaining or improving reliability.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The conductive structure is given multi-functionality through the modification process, serving simultaneously as the conductive element, adhesion layer, and diffusion barrier. This universal approach eliminates the need for multiple specialized layers, reducing the overall manufacturing time and process complexity while achieving the same or better performance.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method results in conductive structures with fewer defects and lower resistance, improving the performance and adhesion of semiconductor structures without the need for additional adhesion or diffusion barrier layers.

Implementation Method 1

introducing a first gas on the dielectric structure to form a first conductive structure on the dielectric structure

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Implementation Method 2

introducing a second gas on the first conductive structure to modify the first conductive structure

Methodology Applied
Scientific EffectSurface passivation: Adsorption

Implementation Method 3

introducing a third gas on the dielectric structure to form a second conductive structure on the dielectric structure

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Data Source

PatentUS11823896B2Conductive structure formed by cyclic chemical vapor deposition
Publication Date: 2023.11.21 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US11823896B2 patent drawing
  • US11823896B2 patent drawing
  • US11823896B2 patent drawing

AI summary

A method for forming a semiconductor structure is provided. The method includes forming a dielectric structure on a semiconductor substrate, introducing a first gas on the dielectric structure to form first conductive structures on the dielectric structure, and introducing a second gas on the first conductive structures and the dielectric structure. The second gas is different from the first gas. The method also includes introducing a third gas on the first conductive structures and the dielectric structure to form second conductive structures on the dielectric structure. The first gas and the third gas include the same metal.