Cyclic Host Compounds for Low-Voltage OLED Color Purity

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Solution Overview

Problem

Existing organic electroluminescence devices face challenges in service life, efficiency, operating voltage, and color purity, particularly in phosphorescent devices, with matrix materials playing a crucial role in these properties.

Innovation Solution

Development of specific cyclic compounds, including structures of formula (I), which can be used as matrix materials, hole transport materials, or electron blocking materials, enhancing device performance by improving service life, efficiency, and reducing operating voltage while maintaining low refractive index and achieving excellent color purity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If phosphorescent organometallic complexes are used as emitting materials, then energy efficiency and power efficiency are improved, but service life is reduced

Engineering Contradiction:
Improveenergy efficiencyVSAvoidservice life
Core Design Contradiction:
Use of energy by moving objectVSDuration of action of stationary object

Solution Approach 1:

The patent introduces cyclic compounds as host materials that mediate between the phosphorescent organometallic complexes and the device environment. These host materials protect the sensitive phosphorescent emitters while enabling efficient triplet state utilization, thus maintaining high energy efficiency while extending service life through improved material stability and reduced degradation.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Use of energy by stationary object

If phosphorescent organometallic complexes are used as emitting materials, then power efficiency is improved, but operating voltage increases

Engineering Contradiction:
Improvepower efficiencyVSAvoidoperating voltage
Core Design Contradiction:
Use of energy by stationary objectVSStress or pressure

Solution Approach 1:

The patent modifies the energy level parameters of the host materials to better match the phosphorescent emitters. By carefully selecting host materials with appropriate HOMO-LUMO levels and triplet energy states, the device achieves efficient energy transfer at lower operating voltages, reducing the voltage penalty typically associated with phosphorescent devices.

Inventive Principle:
Principle #35Parameter changes

3Device complexity

If conventional matrix materials are used, then device structure is simple, but color purity is reduced

Engineering Contradiction:
Improvedevice structureVSAvoidcolor purity
Core Design Contradiction:
Device complexityVSManufacturing precision

Solution Approach 1:

The patent applies local quality optimization by selecting host materials with specific molecular structures and energy level characteristics tailored to each emission color requirement. Different cyclic compounds are chosen for different color regions (red, green, blue) to optimize color purity locally while maintaining overall device structural simplicity.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The compounds lead to organic electroluminescent devices with improved lifetime, efficiency, and reduced operating voltage, along with enhanced color purity, particularly in red and yellow phosphorescent devices, while being adaptable across various applications and temperatures.

Implementation Method 1

The present invention relates to cyclic compounds for use in electronic devices, in particular in organic electroluminescence devices

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 2

there is still room for improvement in electroluminescence devices, especially those exhibiting triplet emission (phosphorescence)

Methodology Applied
Scientific EffectPhosphorescence: Phosphorescence

Data Source

PatentEP4519383B1Cyclic compounds for organic electroluminescent devices
Publication Date: 2026.01.14 MERCK PATENT GMBH
  • EP4519383B1 patent drawing
  • EP4519383B1 patent drawing
  • EP4519383B1 patent drawing

AI summary

The present invention relates to cyclic compounds which are suitable for use in electronic devices, and to electronic devices, in particular organic electroluminescent devices containing said compounds.