Cyclic Lipopeptide Biosurfactant Anionic Surfactant CMC Reduction

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Solution Overview

Problem

Current methods for reducing the critical micelle concentration (CMC) of anionic surfactants, such as mixing multiple surfactants or combining synthetic anionic surfactants with biosurfactants, do not effectively lower CMC to a significant extent, leading to high usage amounts and environmental concerns.

Innovation Solution

Combining a cyclic lipopeptide biosurfactant, like surfactin, with anionic surfactants, which significantly reduces the CMC, allowing for a substantial decrease in the amount of anionic surfactant required, while being environmentally friendly and safe for use.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If a synthetic anionic surfactant is used to achieve various surfactant functions, then the surfactant can be inexpensively produced and widely utilized, but the surfactant causes environmental damage and harm to living bodies due to its homogenizing function and ease of penetration

Engineering Contradiction:
Improveproduction costVSAvoidenvironmental damage and harm to living bodies
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The invention changes the critical micelle concentration parameter by combining synthetic anionic surfactant with cyclic lipopeptide biosurfactant. This parameter change allows the surfactant mixture to achieve effective cleaning at lower concentrations, reducing environmental impact while maintaining manufacturing feasibility

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite surfactant system by combining synthetic anionic surfactant (sodium linear alkylbenzene sulfonate or sodium alpha-olefin sulfonate) with cyclic lipopeptide biosurfactant (surfactin or its salts). This composite approach leverages the low cost of synthetic surfactants while adding the environmental benefits of biosurfactants, resolving the contradiction between manufacturing ease and environmental harm

Inventive Principle:
Principle #40Composite materials

2Reliability

If the concentration of anionic surfactant is increased to fulfill surfactant functions, then the surfactant activity is sufficient, but the amount of surfactant to be used increases leading to greater environmental impact

Engineering Contradiction:
Improvesurfactant activityVSAvoidamount of surfactant to be used
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The invention changes the critical micelle concentration parameter through surfactant combination, enabling sufficient surfactant activity at lower concentrations. The cyclic lipopeptide biosurfactant modifies the micellization behavior of the anionic surfactant, allowing effective performance with reduced surfactant quantity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention merges synthetic anionic surfactant with cyclic lipopeptide biosurfactant to create a synergistic system. This combination produces a mixed micelle system where the biosurfactant enhances the efficiency of the synthetic surfactant, achieving reliable surfactant activity with reduced total surfactant quantity

Inventive Principle:
Principle #5Merging (Combining)

3Quantity of substance

If multiple surfactants are mixed to reduce critical micelle concentration, then the CMC may be decreased, but the effect is not remarkable and the critical micelle concentration may even be increased

Engineering Contradiction:
Improvecritical micelle concentrationVSAvoideffectiveness of CMC reduction
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The invention achieves remarkable CMC reduction by specifically combining anionic surfactants with cyclic lipopeptide biosurfactants. This specific parameter combination produces consistent and significant CMC reduction, overcoming the unreliable effects observed with other surfactant mixtures

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a specific composite system of anionic surfactant and cyclic lipopeptide biosurfactant that produces reliable CMC reduction. The synergistic interaction in this composite system ensures consistent effectiveness, avoiding the unpredictable results of generic surfactant mixing

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The combination of cyclic lipopeptide biosurfactants with anionic surfactants reduces the CMC by up to 1000 times, minimizing environmental impact and human exposure to anionic surfactants, making the surfactant composition more efficient and safer.

Implementation Method 1

a surfactant has both of a hydrophilic part and a lipophilic part in one molecule, and exhibits various activities such as wash, dispersion, antirust, anticorrosive, moistening, penetration, bubble formation, emulsifying, solubilization and antistat

Methodology Applied
Scientific EffectMicelle formation: Surfactant

Implementation Method 2

The minimum concentration of a surfactant to form the aggregate is referred to as CMC: critical micelle concentration

Methodology Applied
Scientific EffectCritical micelle concentration: Surfactant

Data Source

PatentEP3115104B1Method for reducing critical micelle concentration
Publication Date: 2019.04.24 KANEKA CORP
  • EP3115104B1 patent drawingFigure 1
  • EP3115104B1 patent drawingFigure 2
  • EP3115104B1 patent drawingFigure 3

AI summary

The objective of the present invention is to provide a method for remarkably reducing a critical micelle concentration of an anionic surfactant, which is used in a large amount currently, to reduce the amount to be used. Also, the objective of the present invention is to provide a surfactant composition of which whole critical micelle concentration is remarkably reduced and in which an amount of an anionic surfactant is reduced in comparison with the case of using an anionic surfactant only as a surfactant. The method for reducing a critical micelle concentration of an anionic surfactant according to the present invention is characterized in using a cyclic lipopeptide biosurfactant in combination with the anionic surfactant.