Cyclic Olefin Copolymer Vertical Alignment Layer for Low-Temperature Liquid Crystal Orientation

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Solution Overview

Problem

Existing vertical alignment layers for liquid crystal display devices require high-temperature processes, which are not suitable for flexible display applications, necessitating a solution for achieving effective liquid crystal alignment at lower temperatures.

Innovation Solution

A vertical alignment layer incorporating a cyclic olefin copolymer with specific substituents that allows for excellent liquid crystal alignment even at low temperatures, eliminating the need for high-temperature imidization processes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a polyamic acid heat resistant polymer is applied and heat treatment is performed at high temperature to form a polyimide polymer alignment layer, then liquid crystal alignment is achieved, but the method is not suitable for flexible display applications requiring low temperature processes

Engineering Contradiction:
Improveliquid crystal alignmentVSAvoidheat treatment temperature
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent changes the chemical composition parameters of the alignment layer by using a cyclic olefin copolymer with specific functional groups (carboxylic acid, hydroxyl, or amine groups) instead of polyimide. This compositional parameter change enables the alignment layer to achieve effective liquid crystal alignment at lower temperatures (below 150°C) while maintaining alignment reliability, thus resolving the contradiction between alignment performance and temperature requirements for flexible displays

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite material approach by creating a copolymer structure that combines cyclic olefin backbone with functional groups capable of interacting with liquid crystal molecules. The specific copolymer structure (containing norbornene rings with pendant functional groups) provides both the mechanical properties needed for flexible substrates and the molecular interaction capabilities for effective alignment at low temperatures

Inventive Principle:
Principle #40Composite materials

2Reliability

If the alignment layer uses a polymer structure that interacts strongly with liquid crystal molecules, then alignment effectiveness is improved, but the process temperature requirement increases

Engineering Contradiction:
Improvealignment effectivenessVSAvoidprocess temperature
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent applies local quality by introducing specific functional groups (carboxylic acid, hydroxyl, or amine groups) at localized positions on the cyclic olefin copolymer chain. These functional groups are positioned as pendant groups on the polymer backbone, creating localized interaction sites that strongly interact with liquid crystal molecules. This localized functional group placement enables effective alignment without requiring high temperature processes across the entire material

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent replaces the thermal mechanism (high temperature heat treatment) with a chemical mechanism (molecular interaction between functional groups and liquid crystal molecules). Instead of relying on thermal energy to achieve alignment, the functional groups on the copolymer directly interact with liquid crystal molecules through hydrogen bonding, dipole-dipole interactions, or other molecular forces, enabling alignment at lower temperatures

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The cyclic olefin copolymer-based alignment layer ensures improved interaction with liquid crystal molecules, maintaining alignment stability across various temperature conditions, particularly beneficial for flexible display technologies.

Implementation Method 1

the alignment layer includes an alignment copolymer, etc., to be applied to initial alignment of a liquid crystal molecule... the alignment copolymer included in the alignment layer needs to cause an interaction easily with molecules in the liquid crystal layer

Methodology Applied
Scientific EffectMolecular interaction: Van der Waals Force

Data Source

PatentEP3196236B1Vertical alignment film comprising (CO)polymer of cyclic olefin compound
Publication Date: 2019.04.10 LG CHEM LTD
  • EP3196236B1 patent drawingFigure 1
  • EP3196236B1 patent drawing
  • EP3196236B1 patent drawing

AI summary

The present invention relates to a vertical alignment layer including a cyclic olefin copolymer, and more specifically, the present invention relates to a vertical alignment layer capable of having alignment even in a low temperature process, and exhibiting excellent liquid crystal vertical alignment by including a cyclic olefin copolymer having a specific substituent.