Cyclic Oxy Ether Compounds for Floral-Green and Watery Notes

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Solution Overview

Problem

Existing perfumery compounds lack floral-green and watery notes, and there is a need for novel odorants that can enhance or modify perfuming compositions to impart these specific scents.

Innovation Solution

The use of cyclic oxy ether compounds of formula (I), characterized by a carbon-carbon double bond and specific alkyl or alkenyl groups, as perfuming ingredients to impart floral-green and watery notes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If existing perfumery compounds are used, then perfuming compositions can be formulated, but they lack floral-green and watery notes

Engineering Contradiction:
Improveodor profile varietyVSAvoidfloral-green note presence
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent introduces a new chemical parameter - the carbonyl group on the alkylic ether substituent - which fundamentally changes the odor profile of the compound. This structural modification transforms existing ether compounds into compounds with distinct floral-green and watery notes, directly resolving the contradiction by changing molecular parameters to achieve desired sensory properties

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite molecular structure combining a cyclic ether backbone with a carbonyl-containing alkylic substituent. This composite structure integrates functional groups from different chemical classes (ether and carbonyl) to produce novel organoleptic properties that neither component alone provides, specifically the floral-green and watery notes

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If novel compounds with floral-green notes are discovered, then perfuming compositions gain enhanced odor properties, but the compounds are not previously known in perfumery

Engineering Contradiction:
Improveodor enhancement capabilityVSAvoidprior art knowledge
Core Design Contradiction:
Adaptability or versatilityVSLoss of information

Solution Approach 1:

The patent employs systematic variation of established chemical parameters (carbonyl group position, alkyl chain length, cyclic structure) within known chemical frameworks to generate novel perfumery compounds. This self-service approach allows the inventors to create new odorants using modifications of existing chemical knowledge and structures, rather than relying on complete novel discovery

Inventive Principle:
Principle #25Self-service

Data Source

PatentEP3810567B1Cyclic oxy ether compounds as perfuming ingredients
Publication Date: 2025.10.29 FIRMENICH SA
  • EP3810567B1 patent drawing
  • EP3810567B1 patent drawing
  • EP3810567B1 patent drawing

AI summary

34 Abstract The present invention relates to the use as perfuming ingredients, e.g. to impart odor notes of the floral-green (jasmine like) and watery type, of cyclic oxy ether compounds of formula 5 (I) in the form of any one of its stereoisomers or a mixture thereof, and wherein the dotted line represents a carbon-carbon single or double bond; p represents 0 to 3, preferably 1 to 3; n represents 0 to 2; R represents, independently from each other hydrogen, a C1-C6 alkyl or C2-C6 alkenyl group each optionally substituted by an ester group; R1 represents, 10 independently from each other, a hydrogen atom or a C1-C3 alkyl group.