Cyclic Pulse Discharge Nano Coating for Heat Dissipation

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Solution Overview

Problem

Current methods for preparing conformal coatings, such as Parylene and plasma chemical vapor deposition, face challenges including inadequate thickness, high material costs, strict preparation conditions, and poor heat dissipation and signal transmission properties, which limit their effectiveness in protecting electronic devices from corrosive environments.

Innovation Solution

A method involving high duty ratio pulse discharge with a cyclic pretreatment and coating process, using a combination of mono-functional and poly-functional monomers, to form a compact, multi-layer nano coating that enhances bonding and protective properties while maintaining efficient heat dissipation and signal transmission.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If Parylene coating is applied to provide effective corrosion protection, then the coating thickness must be increased to 30 micrometers or greater, but this causes poor heat dissipation and signal blocking

Engineering Contradiction:
Improvecorrosion protectionVSAvoidheat dissipation
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent employs an ultrathin nano coating film with thickness of 1-100 nanometers (one-thousandth to one-millionth of traditional coating thickness) to provide corrosion protection. This ultra-thin film structure allows heat and signals to pass through while maintaining protective functionality, resolving the contradiction between protection effectiveness and heat dissipation.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The patent changes the thickness parameter from micrometer level (30 micrometers or greater) to nanometer level (1-100 nanometers), representing a thousand-fold reduction. This parameter change enables the coating to provide adequate corrosion protection while allowing heat and electromagnetic signals to penetrate through, eliminating the trade-off between protection and thermal/electrical performance.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If traditional plasma chemical vapor deposition is used to form conformal coating, then the coating provides corrosion protection, but the preparation conditions are strict and material costs are high

Engineering Contradiction:
Improvecorrosion protectionVSAvoidpreparation conditions
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent introduces cyclic large-duty-ratio pulse discharge mode with specific parameters (frequency 1-1000 Hz, duty ratio 1:1 to 1:1000, power density 0.1-10 W/cm²) to enable effective conformal coating formation under more relaxed conditions compared to traditional continuous plasma methods, reducing material costs and simplifying preparation requirements.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs cyclic pulse discharge with periodic on-off cycles to control plasma formation and monomer deposition. This periodic action allows for better control of coating thickness and uniformity while reducing overall energy input and material requirements, making the process more economical and easier to manufacture.

Inventive Principle:
Principle #19Periodic action

3Loss of energy

If low duty ratio pulse discharge is used for coating preparation, then energy consumption is reduced, but the coating compactness and durability are insufficient

Engineering Contradiction:
Improveenergy consumptionVSAvoidcoating durability
Core Design Contradiction:
Loss of energyVSStrength

Solution Approach 1:

The patent uses cyclic pulse discharge with optimized duty ratios (1:1 to 1:1000) and frequencies (1-1000 Hz) to balance energy efficiency with coating quality. The periodic plasma generation creates sufficient energy input during active phases to ensure compact coating structure and strong adhesion, while the off-phases allow for controlled deposition and reduce overall energy consumption.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The patent optimizes multiple parameters including power density (0.1-10 W/cm²), frequency (1-1000 Hz), and duty ratio (1:1 to 1:1000) to achieve the optimal balance between energy consumption and coating durability. These parameter changes enable the formation of compact, durable coatings with excellent adhesion while maintaining low energy input compared to traditional continuous plasma methods.

Inventive Principle:
Principle #35Parameter changes

4Reliability

If thick coating is applied to enhance protection, then corrosion resistance is improved, but heat dissipation and signal transmission are affected

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidsignal transmission
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The patent applies an ultrathin nano coating film (1-100 nanometers thick) that acts as a flexible protective barrier. This ultra-thin structure provides adequate corrosion resistance while being transparent to heat and electromagnetic signals, allowing energy and signals to pass through with minimal attenuation, thus resolving the contradiction between protection and signal transmission.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The patent changes the coating thickness parameter from traditional thick coatings (micrometer scale) to ultrathin nano coatings (nanometer scale, 1-100 nm). This thousand-fold reduction in thickness maintains corrosion protection functionality while eliminating the blocking effect on heat and signals, allowing all three requirements to be satisfied simultaneously.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method achieves a more compact and durable nano coating with improved resistance to water, moisture, acids, and alkalines, extending the service life of electronic devices and reducing material usage, thus enhancing production efficiency and environmental friendliness.

Implementation Method 1

enable the plasma discharge, and carry out chemical vapor deposition

Methodology Applied
Scientific EffectPlasma discharge: Plasma

Implementation Method 2

carry out chemical vapor deposition; Plasma chemical vapor deposition (PCVD) is a technology that uses plasma to activate reaction gases

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Data Source

PatentEP3611291B1Method for preparing multi-functional protective NANO coating by means of cyclical large-duty-ratio pulse discharge
Publication Date: 2023.10.04 JIANGSU FAVORED NANOTECHNOLOGY CO LTD

AI summary

A method for cyclically preparing a multi-functional nano protective coating through high duty ratio pulse discharge is provided, which belongs to the field of plasma technologies. This method vacuums a reaction chamber and then sends in an inert gas; makes the substrate to move in the reaction chamber; sends a monomer vapor into the reaction chamber and carries out chemical vapor deposition process, which consists of pretreatment and coating phases. In the pretreatment phase, the plasma discharge mode is high power continuous discharge; in the coating phase, the plasma discharge mode is high duty ratio pulse discharge. The pretreatment and coating phases are cyclically repeated at least once. During the coating process, the introduction of this cycle is conducive to generating more active sites on the substrate, improving the effective coating, and resulting in a more compact coating structure. A nano coating with a multiple layer composite structure is obtained, which provides multiple layers of protection for the product itself. There is a more compact coating structure microscopically, while on the macro level, it shows excellent hydrophobic property, adhesive force, acid and alkali resistance, mechanical property, and dampness and heat resistance performance.