Cyclodextrin Dye Complex for Stable Light Conversion Films

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Solution Overview

Problem

Existing light conversion devices face challenges in achieving high durability, quantum efficiency, and stability, particularly with organic fluorescent dyes, which suffer from agglomeration and reduced thermal stability.

Innovation Solution

A dye complex is formed using a polymer with two or more cyclodextrin units, where the dye is incorporated within the cyclodextrin units, enhancing dispersion stability and preventing agglomeration, thereby improving thermal stability and quantum efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If the concentration of organic fluorescent dye is increased to increase conversion efficiency and intensity of converted light, then light emission efficiency is improved, but extinction phenomenon occurs and stability to heat or light is reduced

Engineering Contradiction:
Improvelight emission efficiencyVSAvoidstability to heat or light
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

Cucurbituril acts as an intermediary host molecule that forms a complex with the organic fluorescent dye. The host-guest complex structure provides a protective environment for the dye, enhancing its thermal and light stability while maintaining high light emission efficiency. The cucurbituril cavity encapsulates the dye molecule, preventing aggregation and degradation.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention creates a composite material system consisting of cucurbituril host and fluorescent dye guest. This composite structure combines the stability properties of the cyclodextrin-based cucurbituril with the fluorescent properties of the organic dye, achieving both high stability and high light emission efficiency simultaneously.

Inventive Principle:
Principle #40Composite materials

2Reliability

If inorganic fluorescent material is used to achieve high color purity and physical stability, then color reproduction is improved, but cost increases and light emission efficiency decreases

Engineering Contradiction:
Improvecolor purityVSAvoidcost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The invention replaces expensive inorganic fluorescent materials with cheaper organic fluorescent dyes that are protected by cucurbituril. The organic dye-cucurbituril complex provides comparable stability and color purity at lower cost, making the light conversion device more economically viable while maintaining performance.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Productivity

If nano-crystal fluorescent material is used to achieve high quantum efficiency and monochromatic light emission, then light emission intensity is improved, but raw material cost increases and heat resistance decreases

Engineering Contradiction:
Improvequantum efficiencyVSAvoidheat resistance
Core Design Contradiction:
ProductivityVSTemperature

Solution Approach 1:

Cucurbituril serves as a protective intermediary that shields the organic fluorescent dye from thermal degradation. The host-guest complex structure provides thermal stability comparable to or exceeding that of nano-crystal materials, while maintaining high quantum efficiency and avoiding the high raw material costs of nano-crystals.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The approach results in a light conversion film that maintains high light emission efficiency and stability, capable of converting near ultraviolet to visible light with improved color purity and reproducibility, suitable for applications like white LEDs.

Implementation Method 1

a dye included in the cyclodextrin unit of the polymer

Methodology Applied
Scientific EffectInclusion complex formation: Solvation

Implementation Method 2

a light conversion device absorbing light in a region ranging from a near ultraviolet ray to a visible ray from a light source to perform conversion into a visible ray having a predetermined wavelength

Methodology Applied
Scientific EffectFluorescence: Fluorescence

Data Source

PatentUS10323104B2Dye complex, photoconversion film and electronic element including same
Publication Date: 2019.06.18 LG CHEM LTD
  • US10323104B2 patent drawing
  • US10323104B2 patent drawing
  • US10323104B2 patent drawing

AI summary

The present specification relates to a dye complex, a light conversion film, and an electronic device including the same.