Solid Ozone Storage Material Using Cyclodextrin Inclusion

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Solution Overview

Problem

Ozone is unstable and difficult to store due to its high reactivity and short half-life, posing challenges for its practical use and storage, especially in large quantities, and existing methods are either dangerous or inefficient.

Innovation Solution

A process to produce a solid ozone storage material using cyclodextrins and/or cyclodextrin derivatives, which are contacted with ozone to stabilize and store it, allowing for long-term storage and easy handling.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If ozone is stored in its pure state or mixture under ambient conditions, then storage capacity is improved, but stability and lifetime deteriorate due to rapid decomposition

Engineering Contradiction:
Improveozone storage capacityVSAvoidozone stability
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The patent introduces cyclodextrin as an intermediary substance that forms an inclusion complex with ozone. The cyclodextrin cavity encapsulates the ozone molecule, acting as a mediator that protects ozone from decomposition while enabling storage. This resolves the contradiction by providing both storage capacity and stability through the host-guest complexation mechanism.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the physical state parameter of ozone from gaseous to solid form through inclusion complexation with cyclodextrin. This parameter change enables ozone to be stored in solid form at ambient conditions, simultaneously achieving high storage capacity and enhanced stability by altering the fundamental state of ozone.

Inventive Principle:
Principle #35Parameter changes

2Ease of operation

If an on-site ozoniser is used to produce ozone, then ozone availability is improved, but device complexity and operational difficulty increase

Engineering Contradiction:
Improveozone availabilityVSAvoidozoniser complexity
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The patent applies preliminary action by pre-complexing ozone with cyclodextrin to create a stable solid material that can be stored and transported. This eliminates the need for on-site ozone generation equipment, as the ozone is already prepared and stabilized in advance, thereby simplifying the system and improving ease of operation.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent extracts the ozone generation function from the storage and usage system. By separating ozone production (done in advance) from storage and application, the complex ozoniser device is removed from the point-of-use system, leaving only the simple solid ozone-cyclodextrin material that can be easily handled and applied.

Inventive Principle:
Principle #2Taking out (Extraction)

3Stability of the object's composition

If temperature is lowered to extend ozone lifetime, then stability is improved, but operational complexity and cost increase

Engineering Contradiction:
Improveozone stabilityVSAvoidtemperature control complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The patent changes the stabilization mechanism from temperature-dependent (requiring low temperatures) to chemical structure-dependent (using cyclodextrin inclusion complex). This parameter change allows ozone to be stabilized at ambient temperatures without complex cooling systems, resolving the contradiction between stability and operational complexity.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solid ozone storage material can maintain ozone for several days at ambient temperature, offering a high storage capacity and enabling separation of production and use locations, while being safe and easy to handle.

Implementation Method 1

contacting cyclodextrins and/or cyclodextrin derivatives in solid form with a gas comprising ozone whereby a solid ozone storage material is obtained

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS12434967B2Method for preparing a solid material for storing ozone, the material and the uses thereof
Publication Date: 2025.10.07 ECOLE DING DE PURPAN
  • US12434967B2 patent drawing
  • US12434967B2 patent drawing
  • US12434967B2 patent drawing

AI summary

The present invention relates to a method and a unit for preparing a solid material for storing ozone, said method comprising contacting cyclodextrins and/or derivatives of cyclodextrins in solid form with a gas comprising ozone, by means of which a solid material for storing ozone is obtained. The present invention also relates to the material thus prepared and to the uses thereof.