Cyclopentane Liquid Crystals for Low Threshold Voltage

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Solution Overview

Problem

There is a need for liquid crystal displays with improved performance, specifically those having low threshold voltage, which is inversely proportional to the dielectric anisotropy of the mixture, to simplify electronics and enable space and weight savings.

Innovation Solution

The development of liquid crystal compounds and mixtures incorporating a cyclopentane group and at least two other rings, including a fused ring system, to achieve high dielectric constants, both positive and negative, for use in liquid crystal displays.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If liquid crystal mixtures with large dielectric constant are used to reduce threshold voltage, then threshold voltage is lowered, but device complexity and manufacturing difficulty increase due to the need for specific molecular structures

Engineering Contradiction:
Improvethreshold voltageVSAvoidmixture composition complexity
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The patent changes the molecular structure parameters by introducing cyclopentane rings and fused ring systems, which fundamentally alters the dielectric properties of the liquid crystal molecules. This structural parameter change enables achieving large dielectric constants through specific molecular geometry rather than complex mixture formulations.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite molecular structures by combining cyclopentane rings with fused ring systems in specific configurations. These composite molecular architectures provide both the desired dielectric properties and structural stability, simplifying the overall mixture design while achieving low threshold voltage.

Inventive Principle:
Principle #40Composite materials

2Reliability

If complex liquid crystal mixtures are formulated to achieve desired properties, then performance is improved, but manufacturing precision and cost increase

Engineering Contradiction:
Improveliquid crystal display performanceVSAvoidmixture formulation precision
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent modifies key molecular parameters by incorporating cyclopentane rings and fused ring systems, which inherently provide the desired liquid crystal properties. This approach shifts from precise mixture formulation to controlled molecular structure design, reducing manufacturing precision requirements while maintaining performance.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces specific local structural features (cyclopentane rings at terminal positions, fused ring systems at core positions) that locally provide the necessary dielectric and mesogenic properties. This localized structural quality ensures consistent performance without requiring complex overall mixture formulations.

Inventive Principle:
Principle #3Local quality

3Reliability

If terminal cyclopentane groups are incorporated into liquid crystal molecules, then dielectric anisotropy is enhanced, but molecular synthesis complexity increases

Engineering Contradiction:
Improvedielectric anisotropyVSAvoidmolecular synthesis
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent segments the liquid crystal molecule into distinct functional regions: terminal cyclopentane groups providing dielectric properties, core fused ring systems providing mesogenic properties, and connecting alkyl chains providing flexibility. This segmentation allows independent optimization and simplifies the synthesis pathway for each segment.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent employs preliminary action by first establishing the core fused ring structure with desired mesogenic properties, then adding terminal cyclopentane groups in a subsequent step. This sequential approach simplifies synthesis by breaking down the complex molecular construction into manageable stages with standardized intermediates.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

These compounds and mixtures effectively lower the threshold voltage, increase switching speed, and enhance other properties, improving the overall performance of liquid crystal displays.

Implementation Method 1

The threshold voltage is inversely proportional to the dielectric anisotropy of the mixture. Therefore, one way to produce a liquid crystal mixture having a low threshold voltage is the use of mixtures having a large (positive or negative) dielectric constant.

Methodology Applied
Scientific EffectDielectric constant: Dielectric Permittivity

Data Source

PatentUS10745617B2Liquid crystals comprising cyclopentane groups
Publication Date: 2020.08.18 JINGMEISHENG OPTOELECTRIC MATERIAL NANJING
  • US10745617B2 patent drawing
  • US10745617B2 patent drawing
  • US10745617B2 patent drawing

AI summary

Provided are liquid crystal compounds and mixtures incorporating the same. The liquid crystal compounds of the invention generally comprise a cyclopentane group and at least two other rings. In one embodiment, the liquid crystal compounds of the invention comprise a cyclopentane group and at least two other rings, one of which is a fused ring system.