Cyclopropene Complex Water Retention

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Solution Overview

Problem

Existing methods for preparing cyclopropene complexes often result in the loss of cyclopropene due to water removal, leading to compositions with high water content and low cyclopropene levels.

Innovation Solution

A composition comprising cyclopropene complex with 2-10% water by weight and a mole ratio of cyclopropene to molecular encapsulating agent between 0.92:1 to 1.5:1, prepared by adding water, cyclopropene, and molecular encapsulating agent to a continuous reactor with controlled residence time, followed by water removal.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If water is removed from the cyclopropene complex solution, then the composition can be stored and handled as a powder, but cyclopropene is released and lost from the complex

Engineering Contradiction:
Improvestorage and handling as powderVSAvoidcyclopropene loss
Core Design Contradiction:
Ease of manufactureVSLoss of substance

Solution Approach 1:

The patent applies parameter changes by carefully controlling the water content to remain within 2-10% rather than completely removing it. This partial retention of water prevents cyclopropene release while still enabling powder form storage and handling, thus resolving the contradiction between ease of manufacture and substance loss.

Inventive Principle:
Principle #35Parameter changes

2Stability of the object's composition

If water is completely removed to achieve low water content, then storage stability is improved, but cyclopropene levels decrease due to release during removal

Engineering Contradiction:
Improvestorage stabilityVSAvoidcyclopropene level
Core Design Contradiction:
Stability of the object's compositionVSQuantity of substance

Solution Approach 1:

The patent changes the water content parameter from complete removal to controlled retention at 2-10%. This optimization maintains storage stability while preserving cyclopropene levels by preventing the release that occurs during complete water removal.

Inventive Principle:
Principle #35Parameter changes

3Quantity of substance

If standard water removal processes are used, then the composition can be concentrated, but cyclopropene diffuses into the atmosphere and decomposes

Engineering Contradiction:
Improvecomposition concentrationVSAvoidcyclopropene diffusion and decomposition
Core Design Contradiction:
Quantity of substanceVSObject-generated harmful factors

Solution Approach 1:

The patent applies parameter changes by controlling water content to 2-10% and optimizing the mole ratio of cyclopropene to molecular encapsulating agent. This approach enables concentration of the composition while minimizing cyclopropene diffusion and decomposition through the stabilized complex structure.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process effectively minimizes cyclopropene loss and maintains high cyclopropene levels in the complex, achieving a composition with 2-10% water content and optimal mole ratio, enhancing stability and handling properties.

Implementation Method 1

one or more molecular encapsulating agent encapsulates one or more cyclopropene or a portion of one or more cyclopropene

Methodology Applied
Scientific EffectMolecular encapsulation: Absorption (physical)

Implementation Method 2

subsequently removing water from said material to form said composition

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentEP2100661B1Cyclopropene complex compositions
Publication Date: 2018.05.09 AGROFRESH INC
  • EP2100661B1 patent drawing

AI summary

There is provided a composition comprising (a) one or more cyclopropene complex, and (b) 0-10% water by weight based on the weight of said composition, wherein the mole ratio of cyclopropene in said composition to molecular encapsulating agent in said composition is 0.92:1 or higher, or wherein the composition is in the form of a powder and, in a two-dimensional image of a representative sample of said powder, 20% or more of the area of the images of the particles of said cyclopropene complex, based on the area of all the images of all the particles of said cyclopropene complex in said image of said sample, is in the form of particles of said cyclopropene complex that have width dimension of 10 micrometers or larger. Also provided is a process for making a composition comprising cyclopropene complex.