Cyclopropene Composition with Metal-Complexing Agents

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Solution Overview

Problem

Existing compositions containing cyclopropenes and water often experience reduced activity, which limits their effectiveness in blocking ethylene's detrimental effects on plants, such as premature death and stunted growth.

Innovation Solution

A composition comprising cyclopropenes and metal-complexing agents, which can include chelating agents like EDTA and molecular encapsulating agents like cyclodextrins, is used to enhance the activity of cyclopropenes by reducing interactions with metal ions in water, thereby maintaining their effectiveness in blocking ethylene's effects on plants.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If cyclopropenes are mixed with water for delivery to plants, then the delivery method is simple and cost-effective, but the activity of cyclopropenes is reduced due to interactions with metal ions in water

Engineering Contradiction:
Improvesimplicity of delivery methodVSAvoidactivity of cyclopropenes
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

Metal-complexing agents serve as intermediaries that bind to metal ions in water, preventing these ions from interacting with and deactivating cyclopropenes. The metal-complexing agent captures the harmful metal ions through chelation, allowing cyclopropenes to maintain their biological activity while still being delivered via simple water-based formulations.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The harmful metal ions are effectively extracted or removed from the water-cyclopropene system by introducing metal-complexing agents. These agents selectively bind to metal ions, separating them from cyclopropenes and preventing the deactivating interactions that would otherwise occur in aqueous environments.

Inventive Principle:
Principle #2Taking out (Extraction)

2Reliability

If metal-complexing agents are added to maintain cyclopropene activity, then the effectiveness of blocking ethylene is improved, but the composition becomes more complex

Engineering Contradiction:
Improveeffectiveness of blocking ethyleneVSAvoidcomplexity of composition
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention optimizes parameters such as the concentration of metal-complexing agents, the molar ratio between metal-complexing agent and cyclopropene, and the selection of specific metal-complexing agents to achieve maximum effectiveness while minimizing formulation complexity. By carefully controlling these parameters, the composition maintains high reliability without excessive complexity.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of metal-complexing agents and molecular encapsulating agents in the composition significantly improves the release and activity of cyclopropenes, effectively preventing ethylene-induced damage to plants, as demonstrated by increased cyclopropene availability and efficacy in plant treatment tests.

Implementation Method 1

one or more metal-complexing agents

Methodology Applied
Scientific EffectChelation: Chemical Bonding

Implementation Method 2

molecular encapsulating agents like cyclodextrins

Methodology Applied
Scientific EffectMolecular encapsulation: Physical Containment

Data Source

PatentUS8541344B2Compositions with cyclopropenes and metal-complexing agents
Publication Date: 2013.09.24 AGROFRESH INC
  • US8541344B2 patent drawing
  • US8541344B2 patent drawing
  • US8541344B2 patent drawing

AI summary

A composition is provided that contains a cyclopropene and a metal-complexing agent. Also provided is a method that includes contacting such compositions to plants or plant parts.