Damascene Template Fabrication Without CMP

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Solution Overview

Problem

Conventional silicon wafer-based manufacturing technologies for nanomaterials face limitations such as size accuracy, high cost, and non-uniformity in surface geometry, particularly when using chemical mechanical planarization (CMP) for damascene template fabrication, leading to defects like 'dishing' and 'erosion' and edge exclusion zones.

Innovation Solution

The development of improved methods for fabricating damascene templates using precise lithography and etching techniques to create raised conductive metal features and an interspersed insulating layer, resulting in a planar surface with equal electric potential and reduced non-uniformity, avoiding the need for CMP and its associated defects.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Shape

If chemical mechanical planarization (CMP) is used to achieve flat topography of template surface, then flat surface is obtained, but surface non-uniformity and edge exclusion zones are created

Engineering Contradiction:
Improveflat topographyVSAvoidsurface non-uniformity
Core Design Contradiction:
ShapeVSManufacturing precision

Solution Approach 1:

The patent extracts and removes the problematic CMP process from the fabrication sequence, replacing it with an alternative approach using lithography and etching that achieves flat topography without creating edge exclusion zones or surface non-uniformity

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

Instead of using CMP to remove material and create flat surfaces (which causes edge effects), the patent inverts the approach by using lithographic patterning and etching to create raised conductive features that inherently provide the required flat topography and uniform electric potential

Inventive Principle:
Principle #13The other way round (Inversion)

2Shape

If CMP is used for large area templates, then flat surface is achieved, but dishing and erosion defects occur

Engineering Contradiction:
Improveflat surfaceVSAvoidsurface defects
Core Design Contradiction:
ShapeVSReliability

Solution Approach 1:

The patent replaces the mechanical CMP process with a chemical/physical lithography and etching process, substituting mechanical abrasion with photochemical patterning and selective etching that does not produce dishing or erosion defects

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the fabrication parameters by using controlled lithographic exposure and etching conditions to create uniformly raised conductive features, replacing the variable-pressure CMP process that causes parameter non-uniformity across large areas

Inventive Principle:
Principle #35Parameter changes

3Shape

If CMP is used to achieve uniform flat surface, then planarity is improved, but edge exclusion zones are created reducing usable area

Engineering Contradiction:
ImproveplanarityVSAvoidusable template area
Core Design Contradiction:
ShapeVSArea of stationary object

Solution Approach 1:

The patent performs preliminary lithographic patterning and etching to create raised conductive features before transfer, ensuring that the entire template surface including edges achieves uniform electric potential and flat topography without requiring post-CMP processing that would create edge exclusion zones

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The new method produces damascene templates with significantly diminished surface non-uniformity and edge exclusion zones, enabling efficient and uniform electrophoretic assembly and transfer of nanoelements across larger areas without the limitations of CMP, enhancing productivity and scalability.

Implementation Method 1

depositing an adhesion layer onto the substrate; depositing a conductive metal layer onto the adhesion layer; depositing a chromium mask layer onto the resist layer

Methodology Applied
Scientific EffectPhysical Vapour Deposition: Physical Vapour Deposition

Implementation Method 2

performing lithography to create a two-dimensional pattern of voids in the resist layer

Methodology Applied
Scientific EffectPhotopolymerisation: Photopolymerisation

Implementation Method 3

depositing a chromium mask layer onto the resist layer such that the voids are filled with chromium to form chromium nanostructures

Methodology Applied
Scientific EffectElectrodeposition: Electrodeposition

Implementation Method 4

etching the conducive metal layer which is not covered by the chromium nanostructures, leaving raised conductive metal features

Methodology Applied
Scientific EffectChemical Etching:

Implementation Method 5

depositing an insulating layer onto the surface resulting from step (h) such that the chromium nanostructures and exposed conductive metal surfaces in regions between the raised conductive metal features are covered with the insulating layer

Methodology Applied
Scientific EffectPhysical Vapour Deposition: Physical Vapour Deposition

Implementation Method 6

etching to remove the chromium nanostructures and portions of the insulating layer covering the chromium nanostructures, giving rise to the damascene template

Methodology Applied
Scientific EffectChemical Etching:

Data Source

PatentUS11156914B2Damascene template for nanoelement printing fabricated without chemomechanical planarization
Publication Date: 2021.10.26 NORTHEASTERN UNIV (US)
  • US11156914B2 patent drawing
  • US11156914B2 patent drawing
  • US11156914B2 patent drawing

AI summary

Methods of fabricating a damascene template for electrophoretic assembly and transfer of patterned nanoelements are provided which do not require chemical mechanical polishing to achieve a uniform surface area. The methods include conductive layer fabrication using a combination of precision lithography techniques using etching or building up the conductive layer to form raised conductive features separated by an insulating layer of equal height.