Decoke Effluent Cyclone Separator for Furnace Emission Control

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Solution Overview

Problem

Ethylene cracking furnaces face challenges in meeting stringent emission standards for nitrogen oxides, carbon monoxide, and particulate matter, particularly during decoking operations, as conventional methods fail to effectively remove PM2.5 and can foul selective catalytic reduction (SCR) units.

Innovation Solution

A decoke system comprising a cyclone unit integrated with a lock hopper and valves, where decoke effluent is routed from a furnace decoke motor-operated valve to the cyclone for particle separation, with secondary effluent routed to the firebox for complete combustion, avoiding interference with furnace operations and using CFD modeling for CO and PM2.5 destruction.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-generated harmful factors

If decoke effluent is routed directly to the firebox for combustion, then coke particles are removed, but SCR units may be fouled and emission standards cannot be met

Engineering Contradiction:
Improvecoke particle removalVSAvoidSCR unit operation
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The invention extracts and removes coke particles from the effluent stream using a cyclone separator before the treated effluent is routed to the firebox. This separation step prevents coke particles from reaching and fouling the SCR units while still allowing combustion of the treated effluent.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The cyclone separator acts as an intermediary device between the decoking system and the firebox/SCR unit. It mediates by separating harmful coke particles from the effluent, allowing the cleaned gas stream to proceed to combustion without damaging the SCR catalyst.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Ease of operation

If conventional decoking methods are used, then operation is simple, but emission standards for PM2.5 and CO cannot be met

Engineering Contradiction:
Improvedecoking operationVSAvoidPM2.5 and CO emissions
Core Design Contradiction:
Ease of operationVSObject-generated harmful factors

Solution Approach 1:

The invention replaces simple mechanical venting with a cyclone separation system that uses centrifugal force to remove particles. This mechanical substitution enables effective PM2.5 removal while maintaining operational simplicity through automated cyclone separation.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The invention changes the physical parameters of effluent treatment by using cyclonic separation to remove particles based on size and density, then controlling combustion parameters in the firebox to ensure complete combustion of CO and other combustibles, thereby meeting emission standards.

Inventive Principle:
Principle #35Parameter changes

3Object-generated harmful factors

If SCR unit is installed to meet NOx standards, then NOx emissions are controlled, but system complexity and cost increase

Engineering Contradiction:
ImproveNOx emissionsVSAvoidfurnace system
Core Design Contradiction:
Object-generated harmful factorsVSDevice complexity

Solution Approach 1:

The firebox serves multiple functions: it combusts process gas, provides thermal energy to the cracking coils, and now also serves as a combustion chamber for treating decoked effluent. This multi-functionality eliminates the need for separate treatment equipment, reducing overall system complexity despite the presence of SCR units.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves nearly complete combustion of CO and PM2.5, meeting stringent emission standards without external injections or treatments, ensuring compatibility with existing SCR units and maintaining furnace efficiency.

Implementation Method 1

The decoke cyclone acts to remove most coke particles from the decoke effluent into the lock hopper. The decoke effluent is preferably oriented to make a tangential entry into the decoke cyclone.

Methodology Applied
Scientific EffectCyclone separation: Cyclone Separation

Implementation Method 2

secondary effluent routed to the firebox for complete combustion, achieving nearly complete combustion of CO and PM2.5

Methodology Applied
Scientific EffectCombustion: Combustion

Data Source

PatentUS9630188B2Device and method for decoke effluent processing
Publication Date: 2017.04.25 TECHNIP STONE & WEBSTER PROCESS TECH
  • US9630188B2 patent drawing
  • US9630188B2 patent drawing
  • US9630188B2 patent drawing

AI summary

A device and method for processing decoke effluent to remove particulate matter and pollutant gases is provided, with particular concern for meeting ever more stringent environmental standards.