Decontamination Gel with Stimulus-Responsive Viscosity for Immersion

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Solution Overview

Problem

Existing decontamination methods for surfaces, particularly those with complex geometries or small parts, face challenges in effectively removing contaminants without dispersing toxic agents into the environment. Current gels are not suitable for immersion or soaking processes, limiting their application to large areas and simple shapes.

Innovation Solution

A decontamination frost is developed, comprising a colloidal solution with an inorganic viscosing agent, an agent that varies viscosity in response to external stimuli, and a decontamination active agent. This frost can be applied by soaking or immersion and undergoes a rapid viscosity increase upon stimulus, ensuring adhesion and preventing drips.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If liquid decontaminating solutions are used for immersion or soaking, then the decontamination process is simple and effective for small parts, but the liquid disperses toxic agents into the environment and creates large volumes of chemical effluents

Engineering Contradiction:
Improvedecontamination process simplicityVSAvoidenvironmental contamination and effluent volume
Core Design Contradiction:
Ease of operationVSObject-affected harmful factors

Solution Approach 1:

The decontaminating composition undergoes a phase transition from liquid to gel state. Initially applied as a liquid for easy immersion and penetration, it then transforms into a gel that immobilizes contaminants, preventing their dispersion into the environment while maintaining effective decontamination

Inventive Principle:
Principle #36Phase transitions

Solution Approach 2:

The composition's physical parameters (viscosity, state of matter) are changed through the addition of gelling agents and thickening agents. This allows the same material to provide both liquid-phase penetration and gel-phase containment, resolving the contradiction between operational simplicity and environmental protection

Inventive Principle:
Principle #35Parameter changes

2Loss of substance

If gels are used for decontamination, then chemical effluents are reduced and solid waste is generated, but existing gels are not suitable for immersion or soaking processes

Engineering Contradiction:
Improvechemical effluent volumeVSAvoidapplicability to immersion processes
Core Design Contradiction:
Loss of substanceVSAdaptability or versatility

Solution Approach 1:

The composition exhibits dynamic rheological properties, transitioning from a liquid state during application (enabling immersion) to a gel state during decontamination (reducing effluents). This dynamic behavior allows the same material to satisfy both contradictory requirements at different stages of the process

Inventive Principle:
Principle #15Dynamics

3Stability of the object's composition

If gels with high viscosity are applied to surfaces, then adhesion is improved and drips are prevented, but the gel cannot effectively infiltrate complex geometries and hard-to-reach areas

Engineering Contradiction:
Improvegel adhesion and drip preventionVSAvoidcoverage of complex surfaces
Core Design Contradiction:
Stability of the object's compositionVSArea of stationary object

Solution Approach 1:

The composition is applied in a liquid state first, allowing it to infiltrate complex geometries and coat all surfaces before gelling. This preliminary liquid phase ensures complete coverage, while the subsequent gel phase provides adhesion and prevents drips, resolving the contradiction between penetration and stability

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The decontamination frost effectively treats small and complexly shaped parts by infiltrating all surfaces, including hard-to-reach areas. Upon stimulus, the frost transitions to a high viscosity state, preventing contamination spread and facilitating easy removal of dry residues, thus minimizing environmental impact.

Implementation Method 1

comprising or consisting of: 0.1% to 30% by mass, preferably 0.1% to 25% by mass, more preferably 5% to 25% by mass, more preferably 8% to 20% by mass, relative to the mass of the gel, of at least one inorganic viscosifying agent

Methodology Applied
Scientific EffectViscosifying:

Implementation Method 2

0.01% to 5% by mass, preferably 0.05% to 3% by mass, relative to the mass of the gel, of at least one viscosity variation agent which, when subjected to at least one stimulus, preferably external to the gel, causes a variation in the viscosity of the gel

Methodology Applied
Scientific EffectViscosity variation in response to stimuli:

Implementation Method 3

0.1 to 10 mol/L of gel, preferably 0.5 to 10 mol/L of gel, more preferably 1 to 10 mol/L of gel, of at least one active decontamination agent different from said viscosity variation agent

Methodology Applied
Scientific EffectDecontamination:

Implementation Method 4

0.1% to 2% by mass relative to the mass of the gel, of at least one surfactant and preferably at least one non-ionic surfactant

Methodology Applied
Scientific EffectSurfactant action: Surfactant

Implementation Method 5

The gel according to the invention is particularly suitable for application to contaminated surfaces of parts by soaking, immersion and for decontaminating contaminated surfaces of parts of small size and/or complex shapes

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Data Source

PatentEP2793959B1Decontamination gel and method for decontaminating surfaces by immersion using said gel
Publication Date: 2025.04.30 COMMISSARIAT A LENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
  • EP2793959B1 patent drawingFigure 1A~3C
  • EP2793959B1 patent drawingFigure 4A~6
  • EP2793959B1 patent drawingFigure 7~8

AI summary

The invention relates to a decontamination gel consisting of a colloidal solution including: at least one inorganic viscosity-increasing agent, at least one agent for rapidly altering the viscosity, which, when exposed to at least one stimulus, causes a rapid and large variation in the viscosity of the gel, at least one active decontamination agent, at least one surfactant, and optionally at least one superabsorbent polymer, the remainder consisting of a solvent. The invention also relates to a method for decontaminating a part, in particular a part that is small and/or has complex shape, by coating same with a film of said gel.