Deep Trench Etching in Microelectronic Substrates

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Solution Overview

Problem

Existing etching methods for deep trenches in microelectronic components either produce slow results with surface defects or quickly produce irregular sidewalls, making it difficult to achieve deep trenches with low form factors and smooth, passivated sidewalls necessary for efficient component operation.

Innovation Solution

A method involving pulsed plasma anisotropic ion etching with a series of elementary cycles, including deposition of a passivation layer and two etch sequences: a high-power sequence to access the substrate and a lower-power sequence to control the trench profile, using fluorinated plasma and specific power and frequency settings to prevent over-etching and ensure smooth sidewalls.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If plasma-based ion etching is used to etch trenches quickly for mass production, then productivity is improved, but the sidewalls become irregular with overhangs and notches that block subsequent treatments

Engineering Contradiction:
Improveetching speedVSAvoidsidewall regularity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The etching process is divided into multiple sequential elementary cycles, each consisting of a deposition step followed by an etching step. This segmentation allows the process to build the trench incrementally while maintaining sidewall regularity through repeated thin layer deposition and removal, preventing the formation of large overhangs and notches that would block subsequent treatments.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The method employs periodic alternation between deposition and etching phases within each elementary cycle. This periodic action creates a self-regulating process where each deposited layer is subsequently etched away, preventing accumulation of material that would form blocking overhangs, while maintaining continuous forward progress of the trench etching.

Inventive Principle:
Principle #19Periodic action

2Manufacturing precision

If dry etching is used to restrict formation of surface defects, then sidewall quality is improved, but the etching process becomes very slow and incompatible with mass production

Engineering Contradiction:
Improvesidewall qualityVSAvoidetching speed
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The method changes the parameters of plasma-based ion etching by controlling the deposition thickness to be very thin (on the order of nanometers) and using specific plasma conditions that allow for anisotropic etching with reduced sidewall damage. This enables faster etching rates while maintaining sidewall quality through precise parameter control rather than using slow dry etching methods.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The process creates a composite structure during each elementary cycle by depositing a passivation layer that is then partially removed by etching. This composite approach of combining deposition and etching in sequence allows the trench to be etched faster while the deposited material protects sidewalls from excessive damage, improving both speed and quality.

Inventive Principle:
Principle #40Composite materials

3Reliability

If the trench form factor is reduced to improve component isolation, then component performance is improved, but sidewall surface defects increase and become more problematic

Engineering Contradiction:
Improvecomponent isolationVSAvoidsidewall surface defects
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

A passivation layer is deposited on the trench sidewalls before the etching step in each elementary cycle. This preliminary action protects the sidewalls from damage during etching, reducing the formation of surface defects. The passivation layer is then partially removed by the etching process, allowing the trench to be formed while maintaining clean, defect-free sidewalls suitable for low form factor applications.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables rapid production of deep trenches with very low form factors and smooth, passivated sidewalls, facilitating subsequent treatments like passivation layer deposition and improving component performance by reducing noise and quantum efficiency loss.

Implementation Method 1

deposition of a passivation layer on the sidewalls and the bottom of the trench portion etched during previous cycles

Methodology Applied
Scientific EffectPhysical Vapour Deposition: Physical Vapour Deposition

Implementation Method 2

deposition of a passivation layer on the sidewalls and the bottom of the trench portion etched during previous cycles

Methodology Applied
Scientific EffectChemical Vapour Deposition: Chemical Vapour Deposition

Implementation Method 3

pulsed plasma anisotropic ion etching of the trench portion etched during previous cycles

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 4

pulsed plasma anisotropic ion etching of the trench portion etched during previous cycles

Methodology Applied
Scientific EffectIon bombardment: Ion Beam

Data Source

PatentUS8796148B2Method for producing a deep trench in a microelectronic component substrate
Publication Date: 2014.08.05 STMICROELECTRONICS (CROLLES 2) SAS
  • US8796148B2 patent drawing
  • US8796148B2 patent drawing
  • US8796148B2 patent drawing

AI summary

A method for producing a deep trench in a substrate includes a series of elementary etch cycles each etching a portion of the trench. Each elementary cycle includes deposition of a passivation layer on the sidewalls and the bottom of the trench portion etched during previous cycles; followed by pulsed plasma anisotropic ion etching of the trench portion etched during previous cycles, the etching; being implemented in an atmosphere comprising a passivating species; and including a first etch sequence followed by a second etch sequence of less power than the power of the first etch sequence. The first etch sequence etches the passivation layer deposited in the bottom of the portion so as to access the substrate and etches the free substrate at the bottom of the portion while leaving a passivation layer on sidewalls of the portion.