Defect Capping for Reduced Defect Density Epitaxial Layers

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Solution Overview

Problem

Current methods for growing GaN epitaxial layers often result in high defect densities, which hinder the development of scalable GaN-based devices due to varying microstructural quality across the wafer, necessitating a method to achieve uniform low defect density across the entire epitaxial layer.

Innovation Solution

A defect capping method involving preferential polishing or etching to create a decorated substrate surface with surface recess regions, followed by deposition and patterning of a capping layer to restrict epitaxial growth over defect regions, allowing selective epitaxy to form a reduced defect density epitaxial layer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If selective epitaxial growth is used to reduce defect density locally, then defect density in specific regions is reduced, but regions of varying microstructural quality are created across the wafer

Engineering Contradiction:
Improvedefect densityVSAvoidmicrostructural quality uniformity
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

The substrate surface is pre-treated with preferential polishing or etching to create surface recess regions at defect locations before epitaxial growth begins. A capping layer is then deposited to fill these recesses, preventing defect propagation during subsequent epitaxial growth. This preliminary preparation ensures uniform microstructural quality across the entire wafer while achieving low defect density throughout the epitaxial layer.

Inventive Principle:
Principle #10Preliminary action

2Productivity

If conventional epitaxial growth is used on substrates with high defect density, then the process is simple and scalable, but the epitaxial layer inherits high defect density from the substrate

Engineering Contradiction:
Improveepitaxial growth rateVSAvoiddefect density
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The harmful defect regions on the substrate surface are selectively removed or isolated through preferential polishing or etching, creating surface recess regions that are then filled with a capping layer. This extraction of defect regions prevents them from propagating into the epitaxial layer, allowing high-rate epitaxial growth to proceed while maintaining low defect density in the final product.

Inventive Principle:
Principle #2Taking out (Extraction)

3Manufacturing precision

If the substrate is covered with patterned masking layer for selective epitaxial growth, then defect density is reduced locally, but the process complexity increases

Engineering Contradiction:
Improvedefect densityVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

Instead of using complex patterned masking layers that require precise alignment and multiple processing steps, the invention uses a simple capping layer deposited over the entire surface. The capping layer is selectively removed or remains only where needed, functioning as a temporary protective element that simplifies the overall process while achieving the same defect reduction goal.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach achieves a uniform microstructure with significantly lower defect density across the epitaxial layer, reducing growth stresses and enabling the use of lower-cost bulk substrates, thereby enhancing the performance and scalability of GaN-based devices.

Implementation Method 1

preferential polishing or etching the crystalline defect or amorphous regions relative to the crystalline non-defect regions

Methodology Applied
Scientific EffectPreferential etching:

Implementation Method 2

A capping layer is deposited on the decorated substrate surface

Methodology Applied
Scientific EffectDeposition: Deposition (physical)

Implementation Method 3

Selective epitaxy is then used to form the epitaxial layer, wherein the capping layer in the surface recess regions restricts epitaxial growth of the epitaxial layer over the surface recess regions

Methodology Applied
Scientific EffectEpitaxy: Epitaxy

Data Source

PatentUS9218954B2Defect capping method for reduced defect density epitaxial articles
Publication Date: 2015.12.22 ENTEGRIS INC
  • US9218954B2 patent drawing
  • US9218954B2 patent drawing
  • US9218954B2 patent drawing

AI summary

A method for forming an epitaxial layer on a substrate surface having crystalline defect or amorphous regions and crystalline non-defect regions includes preferential polishing or etching the crystalline defect or amorphous regions relative to the crystalline non-defect regions to form a decorated substrate surface having surface recess regions. A capping layer is deposited on the decorated substrate surface to cover the crystalline non-defect regions and to at least partially fill the surface recess regions. The capping layer is patterned by removing the capping layer over the crystalline non-defect regions to form exposed non-defect regions while retaining the capping layer in at least a portion of the surface recess regions. Selective epitaxy is then used to form the epitaxial layer, wherein the capping layer in the surface recess regions restricts epitaxial growth of the epitaxial layer over the surface recess regions.