Defect Spin Localization Using Electron Mapping Beyond Optical Resolution

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Solution Overview

Problem

Existing methods for imaging defects in materials, particularly solids, are limited by diffraction resolution, preventing the accurate localization of closely spaced defects, especially in quantum applications where higher spatial resolution is necessary.

Innovation Solution

A method involving electron excitation and mapping of emitted electrons from defects using aberration-corrected transmission electron microscopy, combined with electron optics and detectors, achieves spatial resolutions down to 0.1 nm, enabling precise localization of defects.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If optical detection with high numerical aperture microscope objective is used, then defect localization is achieved, but spatial resolution is limited to half the wavelength of detection light

Engineering Contradiction:
Improvespatial resolutionVSAvoiddetection capability
Core Design Contradiction:
Measurement precisionVSEase of operation

Solution Approach 1:

The patent replaces optical detection with electron-based detection. Instead of using photons and optical microscopes, the invention uses electrons excited from defects, detected by electron optics and electron multipliers, achieving spatial resolution limited only by electron wavelength rather than light wavelength.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the detection parameter from optical wavelength to electron wavelength. By using electrons with de Broglie wavelengths much smaller than visible light, the spatial resolution improves from hundreds of nanometers to sub-nanometer scale, enabling resolution of closely spaced defects.

Inventive Principle:
Principle #35Parameter changes

2Measurement precision

If pixel-by-pixel scanning methods like STED or STORM are used, then diffraction-limited resolution is surpassed, but imaging speed decreases and large numbers of defects cannot be observed

Engineering Contradiction:
Improvespatial resolutionVSAvoidimaging speed
Core Design Contradiction:
Measurement precisionVSProductivity

Solution Approach 1:

The patent replaces sequential optical scanning with parallel electron detection. The electron optics system can detect multiple defects simultaneously across the entire field of view, eliminating the need for slow pixel-by-pixel scanning while achieving super-resolution through electron's short wavelength.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent creates an electron copy of the defect distribution. By exciting electrons from defects and mapping their positions, the system generates a high-resolution image of all defects simultaneously, rather than reconstructing images through slow sequential scanning of individual pixels.

Inventive Principle:
Principle #26Copying

3Measurement precision

If conventional electron microscopy is used, then high spatial resolution is achieved, but the method cannot specifically localize defects with trapped electrons

Engineering Contradiction:
Improvespatial resolutionVSAvoiddefect-specific detection capability
Core Design Contradiction:
Measurement precisionVSAdaptability or versatility

Solution Approach 1:

The patent applies local quality by making the electron excitation defect-specific. Only electrons associated with defects having trapped electrons are excited and emitted, while electrons in perfect lattice regions remain unaffected. This selective excitation enables specific localization of defects with the high spatial resolution of electron microscopy.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent changes the detection parameter to exploit the unique electronic state of defects. By using excitation energies that match the binding energy of trapped electrons at defects, the system selectively excites and detects only defect-associated electrons, providing defect-specific imaging with nanometer resolution.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method allows for high-resolution imaging of defects with spatial resolutions of 0.1 nm to 20 nm, facilitating quantum applications by resolving interactions between closely spaced spins and enabling quantum computing and sensing.

Implementation Method 1

the electron is excited such that it is emitted from the material

Methodology Applied
Scientific EffectPhotoemission: Photoelectric Effect

Data Source

PatentEP4367508B1Process and device for the spatially resolved localization of defects in materials
Publication Date: 2026.03.18 ARUMUGAM SRI RANJINI
  • EP4367508B1 patent drawingFigure 1
  • EP4367508B1 patent drawingFigure 2
  • EP4367508B1 patent drawing

AI summary

The present invention relates to a method by means of which defects in materials, preferably in solid bodies (18), can be localized with considerably higher spatial resolution than before. With the present invention, such defects can be quickly and economically imaged with high spatial resolution. Above all, with the present invention it is possible to contactlessly spin-selectively excite and capture or image defects in the solid body with high sensitivity, high dynamic range, large field of view and excellent resolution which far exceeds the present capabilities of optical detection processes. Furthermore, with the process according to the invention there is an excellent possibility for detecting spin even in individual images, wherein high contrast of the spin states and better fidelity of reproduction of the spin states are made possible. The device (10) according to the invention and the process according to the invention are also extremely useful for quantum calculation using defect spins in solid bodies (18), for quantum-capable capturing and for quantum-capable measurement networks.