Defoamer Composition for Water-Dilutable Paint Systems

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Solution Overview

Problem

Water-dilutable paint systems face issues with 'popping' or pinholing due to solvent or water evaporation, leading to film defects and limited paint layer thickness, and existing defoamers may affect paint film properties like gloss and adhesion.

Innovation Solution

A defoamer composition comprising glycerides, aliphatic hydrocarbons, and addition products of ethylene oxide and/or propylene oxide onto C8-24 fatty alcohols, which enhances defoaming properties and increases the 'popping' limit without compromising paint film quality.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If water-dilutable paint systems are used, then environmental compatibility is improved, but popping and pinholing defects occur due to water evaporation

Engineering Contradiction:
Improveenvironmental compatibilityVSAvoidfilm defect prevention
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The defoamer composition is added to the water-dilutable paint system before application to preemptively prevent popping and pinholing defects. The composition works during the drying process to counteract the harmful effects of water evaporation before defects can form in the paint film.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The defoamer composition acts as an intermediary substance between the water-dilutable paint system and the popping defect mechanism. It contains specific compounds (glycerides, alcohols, esters) that interfere with bubble formation and stabilization, preventing the evaporation-induced popping that would otherwise occur.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If existing defoamers are used to prevent popping, then film defects are reduced, but paint film properties like gloss and adhesion are compromised

Engineering Contradiction:
Improvepopping preventionVSAvoidpaint film quality
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The invention changes the chemical parameters of the defoamer composition by selecting specific compounds with appropriate molecular weights, functional groups, and hydrophobicity levels. This optimization allows effective popping prevention while maintaining compatibility with the paint film matrix, thus preserving gloss and adhesion properties.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The defoamer composition is formulated as a composite system containing multiple components (glycerides, alcohols, esters, and other additives) that work synergistically. This composite approach allows the composition to perform multiple functions: preventing popping while simultaneously maintaining or enhancing paint film properties like gloss and adhesion.

Inventive Principle:
Principle #40Composite materials

3Quantity of substance

If paint layer thickness is increased to improve coverage, then coating effectiveness is improved, but popping defects increase due to solvent evaporation

Engineering Contradiction:
Improvepaint layer thicknessVSAvoidfilm integrity
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The defoamer composition is incorporated into the paint system beforehand to preemptively address the popping issue that arises with thicker paint layers. It works during application and drying to prevent bubble formation that would otherwise be trapped in thicker coatings, enabling the use of thicker layers without compromising film integrity.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition effectively prevents pinholing and cratering, maintains paint film gloss, and ensures good flow and substrate wetting, allowing for thicker paint layers without defects, thereby improving the appearance and application of water-dilutable paint systems.

Implementation Method 1

one or more addition products of ethylene oxide (EO) and/or propylene oxide (PO) onto C8-24 fatty alcohols

Methodology Applied
Scientific EffectSurface tension reduction: Surfactant

Implementation Method 2

water evaporates from the surface of the paint layer accompanied by the increase in viscosity

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS7893116B2Defoaming compositions for water-dilutable paint systems
Publication Date: 2011.02.22 COGNIS IP MANAGEMENT GMBH

AI summary

A defoamer composition for water-dilutable paint systems includes one or more glycerides; one or more aliphatic hydrocarbons; and one or more addition products of ethylene oxide (EO) and/or propylene oxide (PO) onto C8-24 fatty alcohols.