Degasifying Membrane Module for Process Water Purification

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Solution Overview

Problem

Existing water treatment processes for power plants, particularly those using flue gas desulfurization and gasification wastewaters, face challenges in consistently meeting stringent EPA limits for constituents like selenium, arsenic, and nitrate, with variability in water composition and temperature sensitivity affecting process performance, and conventional evaporative processes producing distillate water with high ion concentrations.

Innovation Solution

The method involves filtering process water through a degasifying membrane module to reduce dissolved gas concentrations before evaporating, using a degasifying membrane module with a pressure differential to diffuse gases into a vacuum chamber, followed by evaporation at reduced pressure and temperature to achieve low ion concentrations in the water vapor.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional evaporative processes are used to treat process water, then water purification is achieved, but the distillate water contains high ion concentrations that fail to meet EPA limits

Engineering Contradiction:
Improveion concentration in treated waterVSAvoidconsistency in meeting EPA limits
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent applies preliminary action by removing dissolved gases from process water before evaporation through a degasifier unit. This pre-treatment step prevents gas interference during subsequent evaporation, enabling consistent production of distillate water with ion concentrations below EPA limits while improving reliability of the purification process

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent replaces conventional high-temperature evaporative systems with a low-temperature evaporation system operating below 212°F. This substitution uses controlled heating with heat exchangers and vacuum conditions to achieve purification at lower temperatures, improving both manufacturing precision of ion removal and reliability of meeting discharge requirements

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Manufacturing precision

If treatment processes are designed to meet strict EPA limits, then water quality improves, but process complexity and operational challenges increase

Engineering Contradiction:
Improvetreated water qualityVSAvoidnumber of treatment steps
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent merges multiple treatment functions into an integrated system where the degasifier and evaporator units work in sequence as a unified process. The degasifier removes dissolved gases and the evaporator concentrates ions in a single continuous flow path, achieving EPA-compliant water quality while reducing operational complexity compared to separate treatment trains

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent applies parameter changes by operating the evaporation process at low temperatures below 212°F under controlled pressure conditions. This parameter modification allows effective ion removal and water purification while simplifying equipment requirements and reducing operational complexity compared to high-temperature conventional evaporation systems

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If existing treatment systems are used, then current water quality standards are met, but they cannot consistently achieve the lower ion concentrations required by new EPA proposals

Engineering Contradiction:
Improveion concentration reductionVSAvoidconsistent compliance with EPA limits
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent applies preliminary action by removing dissolved gases from process water before evaporation through a degasifier unit. This pre-treatment step prevents gas interference during subsequent evaporation, enabling consistent production of distillate water with ion concentrations below EPA limits while improving reliability of the purification process

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent replaces conventional high-temperature evaporative systems with a low-temperature evaporation system operating below 212°F. This substitution uses controlled heating with heat exchangers and vacuum conditions to achieve purification at lower temperatures, improving both manufacturing precision of ion removal and reliability of meeting discharge requirements

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly reduces dissolved ion concentrations in the treated water, meeting EPA limits and producing high-purity water suitable for reuse or discharge, with improved resilience to process upsets and variability, and minimal reagent and maintenance requirements.

Implementation Method 1

diffusing at least a portion of the dissolved gas in the process water across the membrane and into the vacuum chamber to remove at least a portion of the first dissolved gas from the process water

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 2

a vacuum chamber at a second pressure that is less than the first pressure

Methodology Applied
Scientific EffectVacuum: Vacuum

Implementation Method 3

evaporating the filtered process water to create a water vapor

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 4

evaporation at reduced pressure and temperature

Methodology Applied
Scientific EffectPressure reduction: Depressurisation

Data Source

PatentUS8882967B1Systems and methods for purifying process water
Publication Date: 2014.11.11 SOUTHERN CO
  • US8882967B1 patent drawing
  • US8882967B1 patent drawing
  • US8882967B1 patent drawing

AI summary

Disclosed are methods for purifying a process water, which can comprise providing a process water comprising a first concentration of a first dissolved gas and a first concentration of a first dissolved ion, filtering the process water to create a filtered process water comprising a second concentration of the first dissolved gas, and evaporating the filtered process water to create a water vapor comprising a second concentration of the first dissolved ion that is less than the first concentration of the first dissolved ion.