Low-Density High-Strength Degradable Temporary Plugging Agent

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Solution Overview

Problem

Current temporary plugging agents in fracturing technology rely on filter cake formation, which limits the expansion of plugging modes and requires a low-density, high-strength, degradable solution for effective crack steering and reservoir permeability restoration.

Innovation Solution

A temporary plugging agent composed of 60-85% polylactic acid, 5-20% starch, 5-10% polycaprolactone, 2-5% solubilizing agent, and 2-5% toughening agent, with specific ratios and properties, is developed for extrusion molding, allowing for bridge plugging and degradation within the reservoir temperature range.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If traditional filter cake plugging agents are used, then plugging function is achieved, but density is high and strength is insufficient

Engineering Contradiction:
Improveplugging strengthVSAvoidagent density
Core Design Contradiction:
StrengthVSWeight of moving object

Solution Approach 1:

The patent uses composite materials by combining polylactic acid (60-85%), starch (5-20%), and polycaprolactone (5-10%) to create a temporary plugging agent that achieves high strength while maintaining low density. The composite structure allows the material to exhibit both structural integrity and lightweight properties simultaneously.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the physical and chemical parameters of the plugging agent by controlling particle size distribution (1-4mm), density (1.1-1.3g/cm³), and bearing strength (>52MPa) to achieve optimal performance. These parameter adjustments resolve the contradiction between strength and density.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If permanent plugging agents are used, then crack plugging is effective, but reservoir permeability cannot be restored

Engineering Contradiction:
Improveplugging effectivenessVSAvoidpermeability restoration capability
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent applies dynamics by designing a temporary plugging agent that changes its properties over time. The agent provides strong plugging initially, then degrades naturally through biodegradation of polylactic acid and starch components, allowing the reservoir to restore permeability after the plugging function is no longer needed.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The patent implements discarding and recovering by using biodegradable materials that naturally decompose after serving their plugging purpose. The degradation products are environmentally friendly and do not harm the reservoir, allowing permeability recovery while maintaining plugging effectiveness during the required period.

Inventive Principle:
Principle #34Discarding and recovering

3Strength

If high-strength materials are used for bridge plugging, then crack steering capability is improved, but degradation time is excessive

Engineering Contradiction:
Improvebridge plugging strengthVSAvoiddegradation time
Core Design Contradiction:
StrengthVSDuration of action of stationary object

Solution Approach 1:

The patent uses composite materials with different degradation rates - polylactic acid degrades faster than polycaprolactone, creating a staged degradation process. This allows the material to maintain high strength initially, then progressively degrade within 168 hours, balancing bridge plugging strength with timely degradation.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent ensures continuous useful action by maintaining plugging strength throughout the required period, then transitioning smoothly to degradation. The composite structure provides sustained plugging capability followed by controlled breakdown, avoiding sudden loss of function.

Inventive Principle:
Principle #20Continuity of useful action

Data Source

PatentUS11053427B2Low-density, high-strength degradable temporary pugging agent and the preparation method and use thereof
Publication Date: 2021.07.06 PETROCHINA CO LTD
  • US11053427B2 patent drawing
  • US11053427B2 patent drawing

AI summary

A low density, high-strength, degradable temporary plugging agent which includes 60% by weight to 85% by weight of polylactic acid, 5% by weight to 20% by weight of a starch, 5% by weight to 10% by weight of polycaprolactone, 2% by weight to 5% by weight of a solubilizing agent, and 2% by weight to 5% by weight of a toughening agent, based on 100% by weight of the total weight of the agent. The rigid agent can result in bridge plugging in existing cracks, with a significant increase in pressure. The preparation method is simple, the process requirements are low, and industrial production can be realized. When applied to temporary plugging fracturing, under formation conditions, it can be completely degraded within a certain period of time and will not cause secondary damage to the reservoir, while preventing the agent from polluting the formation and the occurrence of pump accidents.