Degradable Polymeric Vehicle for Controlled Chemical Release

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

The harsh and uncontrolled downhole environment in petroleum wells hinders the effective implementation of controlled release technologies, necessitating new chemistries and mechanisms for delivering chemicals like surfactants, breakers, and inhibitors in oilfield operations.

Innovation Solution

Development of delivery systems comprising particles with a polymeric vehicle and cargo, where the vehicle is designed to be degradable under specific conditions, allowing controlled release of chemicals such as scale inhibitors, corrosion inhibitors, and surfactants within the petroleum reservoir.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If controlled release technologies are implemented in downhole environments, then chemical delivery precision is improved, but the harsh and uncontrolled nature of the downhole environment prevents reliable operation

Engineering Contradiction:
Improvechemical delivery precisionVSAvoidsystem reliability in downhole environment
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The vehicle is designed with dynamic degradation properties, transitioning from a stable encapsulated state during delivery to a degradable state under specific downhole conditions (temperature, pressure, chemical environment), enabling controlled release of cargo only when and where needed in the harsh downhole environment

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The system exploits changes in physical and chemical parameters (temperature, pressure, pH, chemical composition) between surface delivery conditions and downhole reservoir conditions to trigger selective cargo release, allowing the vehicle to respond adaptively to the harsh environment rather than being disrupted by it

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If chemicals are delivered to deep reservoir locations, then targeted treatment is improved, but the cost of oilfield chemicals and sensors increases

Engineering Contradiction:
Improvetargeted delivery accuracyVSAvoidcost of chemicals and sensors
Core Design Contradiction:
Manufacturing precisionVSQuantity of substance

Solution Approach 1:

The vehicle system is designed to autonomously navigate to target locations and self-trigger cargo release based on environmental cues encountered in the reservoir, eliminating the need for expensive external sensors and complex control systems while maintaining high targeted delivery accuracy

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The chemical delivery system is segmented into multiple independent vehicle particles, each capable of autonomous targeted delivery and controlled release, allowing precise distribution of chemicals to specific reservoir zones without requiring expensive centralized control infrastructure

Inventive Principle:
Principle #1Segmentation

3Productivity

If the vehicle degrades under downhole conditions, then cargo release is enabled, but the vehicle structural integrity deteriorates

Engineering Contradiction:
Improvecargo release efficiencyVSAvoidvehicle structural integrity
Core Design Contradiction:
ProductivityVSStrength

Solution Approach 1:

The vehicle structure transitions dynamically from a strong, intact encapsulated state during transport and delivery to a degraded, disassembled state under specific downhole conditions, with the degradation process itself being the mechanism for controlled cargo release

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The vehicle is pre-configured with degradation-triggering functionalities and labile crosslinks that remain dormant during delivery but activate automatically upon encountering specific downhole conditions, ensuring timely cargo release without requiring additional activation mechanisms

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables targeted and controlled release of chemicals at the desired location within the petroleum formation, enhancing oilfield operations by ensuring timely and effective delivery of chemicals, even in harsh conditions.

Implementation Method 1

The vehicle can be at least partially degradable via a mechanism selected from the group consisting of thermal degradation, oxidative degradation, chemical degradation, photodegradation, pressure-dependent degradation, ultrasonic degradation, mechanical degradation, and combinations thereof

Methodology Applied
Scientific EffectThermal degradation: Pyrolysis

Implementation Method 2

The vehicle can be at least partially degradable via a mechanism selected from the group consisting of thermal degradation, oxidative degradation, chemical degradation, photodegradation, pressure-dependent degradation, ultrasonic degradation, mechanical degradation, and combinations thereof

Methodology Applied
Scientific EffectOxidative degradation: Oxidation

Implementation Method 3

The vehicle can be at least partially degradable via a mechanism selected from the group consisting of thermal degradation, oxidative degradation, chemical degradation, photodegradation, pressure-dependent degradation, ultrasonic degradation, mechanical degradation, and combinations thereof

Methodology Applied
Scientific EffectPhotodegradation: Photo-oxidation

Implementation Method 4

The vehicle can be at least partially degradable via a mechanism selected from the group consisting of thermal degradation, oxidative degradation, chemical degradation, photodegradation, pressure-dependent degradation, ultrasonic degradation, mechanical degradation, and combinations thereof

Methodology Applied
Scientific EffectUltrasonic degradation: Ultrasonic Vibration

Implementation Method 5

The cargo can be controllably diffusible through the shell

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentUS11078411B2Methods and materials for controlled release of desired chemistries
Publication Date: 2021.08.03 RES TRIANGLE INST
  • US11078411B2 patent drawing
  • US11078411B2 patent drawing
  • US11078411B2 patent drawing

AI summary

The present disclosure relates to delivery and release systems wherein a plurality of particles is provided, and the particles are formed of a vehicle component and a cargo component. The systems and methods particularly can be useful in delivery of various chemicals to a petroleum reservoir. The vehicle component can undergo a change in situ such that at least a portion of the cargo component is released.