Dehumidifying Composition with pH Control and Self-Hardening

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Solution Overview

Problem

Existing dehumidifying compositions face challenges with leakage, corrosion, and lack of visual indicators for saturation, particularly during storage, transport, and use, which can lead to safety and performance issues.

Innovation Solution

A dehumidifying composition comprising calcium chloride (CaCl2), calcium oxide (CaO), and pozzolanic materials with controlled particle sizes and pH levels, along with a pigment-based indicator system, to enhance self-hardening, reduce corrosion, and visually signal saturation, ensuring safety and performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If calcium chloride is used as a desiccant due to its highly hygroscopic nature, then dehumidifying performance is improved, but corrosion risk increases due to high chloride ion levels and low pH in concentrated solutions

Engineering Contradiction:
Improvedehumidifying performanceVSAvoidcorrosion risk
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent converts the harmful low pH property of concentrated calcium chloride solution into a benefit by adding calcium oxide. The calcium oxide reacts with the acidic solution to raise the pH, transforming the corrosive environment into a protective alkaline environment that actually prevents corrosion of steel surfaces while maintaining the dehumidifying performance of the calcium chloride.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent creates a composite dehumidifying composition by combining calcium chloride (for hygroscopic performance), calcium oxide (for pH control and corrosion protection), and pozzolanic materials (for self-hardening). This composite approach allows the system to simultaneously achieve high dehumidifying productivity while eliminating corrosion risks through the synergistic interaction of components.

Inventive Principle:
Principle #40Composite materials

2Reliability

If the composition is made to self-harden to prevent leakage, then safety is improved, but the composition complexity increases due to multiple components and controlled particle sizes

Engineering Contradiction:
Improveleakage preventionVSAvoidcomposition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent implements self-service by incorporating pozzolanic materials that automatically react with calcium hydroxide formed during the dehumidifying process to create a self-hardening effect. This self-hardening mechanism occurs automatically as the desiccant absorbs moisture, progressively stiffening the composition to prevent leakage without requiring external intervention or complex additional systems.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent controls particle size parameters of all components (calcium chloride, calcium oxide, and pozzolanic materials) to optimize both the self-hardening rate and the final mechanical strength. By carefully controlling these physical parameters, the composition achieves reliable leakage prevention while keeping the formulation relatively simple and manufacturable.

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If a visual indicator system is added to show saturation, then ease of operation is improved, but the composition complexity and manufacturing difficulty increase

Engineering Contradiction:
Improvesaturation detectionVSAvoidmanufacturing complexity
Core Design Contradiction:
Ease of operationVSEase of manufacture

Solution Approach 1:

The patent incorporates a pigment-based particulate indicator system that changes color based on the presence of liquid. When the composition is dry, light reflects off particle surfaces giving a lighter appearance; when saturated, the liquid coating absorbs light and the pigment appears darker. This simple optical mechanism provides clear visual saturation indication without requiring complex electronics or additional manufacturing steps.

Inventive Principle:
Principle #32Color changes

Solution Approach 2:

The patent uses a simple pigment-based optical indicator system that copies the saturation state through color change rather than using complex sensors or detection devices. This approach provides reliable ease of operation for saturation detection while maintaining simplicity in manufacturing and composition.

Inventive Principle:
Principle #26Copying

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition effectively prevents leakage, reduces corrosion, and provides a visual indicator for saturation, ensuring robustness and ease of use in desiccant packages, such as those used in shipping containers, with improved stability and safety features.

Implementation Method 1

CaCl2 absorbs moisture over time and forms a concentrated solution, i.e. it is deliquescent.

Methodology Applied
Scientific EffectDeliquescence: Deliquescence

Implementation Method 2

The CaO is also used as a desiccant... However, the presence of CaO raises the pH of the composition.

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Implementation Method 3

the pozzolanic material reacts with calcium hydroxide (which is formed during use) to form a bonding material, perhaps a silicate-based bonding material, that hardens or stiffens the composition

Methodology Applied
Scientific EffectPozzolanic reaction: Chemical Bonding

Implementation Method 4

when the composition is dry, light will be reflected back from many surfaces in the powder mix giving the pigment-based particulate indicator system a lighter appearance and shade. However, when liquid is present on the surface of particles of the composition... more light will fall on the pigment-based particulate indicator system and be absorbed.

Methodology Applied
Scientific EffectLight absorption and reflection: Absorption (EM radiation)

Data Source

PatentEP3912705A1A dehumidifying composition
Publication Date: 2021.11.24 BIRCH CHEM LTD
  • EP3912705A1 patent drawing
  • EP3912705A1 patent drawing

AI summary

The present invention relates to a dehumidifying composition comprising: (i) from 10wt% to 75wt% CaCl2; (ii) from 1wt% to 40wt% CaO; (iii) from 1wt% to 60wt% pozzolanic material; and (iv) optionally, from 0.2wt% to 30wt% pigment-based particulate indicator system, wherein the CaCl2 has a dso particle size of less than 300µm, wherein the CaO has a dso particle size of less than 100µm, wherein the pozzolanic material has a dso particle size of less than 100µm, wherein greater than 90wt% of the particles present in the composition are less than 710µm, and wherein upon dilution in de-ionized water at a concentration of 20w/v% and at a temperature of 20°C, the composition has a pH of greater than 10.0.