Non-Toxic Aircraft Deicing Fluid Using Short Chain Polyols

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Solution Overview

Problem

Existing aircraft deicing/anti-icing fluids contain environmentally unfriendly components such as glycols, toxic surfactants, and non-biodegradable corrosion inhibitors, leading to high aquatic toxicity and residue formation on surfaces, which are not environmentally friendly and do not meet the requirements of SAE/AMS 1428 specifications.

Innovation Solution

The development of environmentally-friendly deicing/anti-icing fluids using short chain polyols, nonionic surfactants, and associative polymers, which reduce toxicity and residue formation, while meeting or exceeding the requirements of SAE/AMS 1428, specifically Type IV anti-icing fluids with a freeze point below -32°C and a Water Spray Endurance Test (WSET) of over 80 minutes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional glycols and toxic surfactants are used in deicing/anti-icing fluids, then the fluid provides effective anti-icing protection, but the fluid causes high aquatic toxicity and environmental harm

Engineering Contradiction:
Improveanti-icing protectionVSAvoidaquatic toxicity
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical composition parameters by replacing conventional glycols (ethylene glycol, diethylene glycol) with propylene glycol and further replacing toxic surfactants (alkylphenol ethoxylates) with nonionic surfactants. This parameter substitution maintains the anti-icing protection function while eliminating aquatic toxicity and environmental harm.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent extracts and removes the harmful components (toxic surfactants like alkylphenol ethoxylates and hazardous glycols) from the fluid formulation, retaining only the beneficial anti-icing components. This extraction eliminates the harmful factors while preserving the protective function.

Inventive Principle:
Principle #2Taking out (Extraction)

2Duration of action of moving object

If thickened fluids with high polymer content are used to achieve long WSET times, then anti-icing protection is improved, but gel-forming residues are left on surfaces

Engineering Contradiction:
ImproveWater Spray Endurance Test timeVSAvoidgel-forming residues
Core Design Contradiction:
Duration of action of moving objectVSObject-generated harmful factors

Solution Approach 1:

The patent changes the thickening mechanism by using associative thickening with specific polymer-surfactant combinations rather than high concentrations of conventional polymers. This parameter change achieves the required WSET time (over 80 minutes for Type IV) while minimizing gel-forming residues on surfaces.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite approach by combining polymers with nonionic surfactants to create an associative thickening system. This composite material system achieves effective thickening for prolonged anti-icing protection without the unwanted gel residues that result from using polymers alone at high concentrations.

Inventive Principle:
Principle #40Composite materials

3Stability of the object's composition

If conventional corrosion inhibitors and additives are used, then fluid stability is maintained, but toxicity and non-biodegradability increase

Engineering Contradiction:
Improvefluid stabilityVSAvoidtoxicity and non-biodegradability
Core Design Contradiction:
Stability of the object's compositionVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical parameters by selecting corrosion inhibitors and additives that are both effective at maintaining fluid stability and environmentally benign. This includes choosing biodegradable and non-toxic compounds that provide the necessary corrosion protection without persisting in the environment.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The new fluid composition is non-toxic to mammals, has lower aquatic toxicity, and minimizes gel-forming residues, providing superior anti-icing protection while being environmentally friendly, suitable for both deicing and anti-icing applications, and reducing the carbon footprint.

Implementation Method 1

these exhibit non-Newtonian (pseudoplastic) behaviors, also referred to as shear-thinning behavior. The shear thinning behavior allows for maximum anti-icing protection due to the uniform coverage by a high viscosity fluid when the aircraft is stationary (zero shear). This fluid greatly thins out during an aircraft take-off roll as the shear rate rapidly increases

Methodology Applied
Scientific EffectShear-thinning behavior: Shear Thinning

Implementation Method 2

The thickened fluids of prior art typically use large molecules (polymers) that typically thicken by molecular entanglement or gelation due to pH adjustment

Methodology Applied
Scientific EffectMolecular entanglement:

Implementation Method 3

The thickened fluids of prior art typically use large molecules (polymers) that typically thicken by molecular entanglement or gelation due to pH adjustment

Methodology Applied
Scientific EffectGelation: Gel

Implementation Method 4

The vast majority of Type II and IV fluids use PG as a freeze-point depressant

Methodology Applied
Scientific EffectFreeze-point depression: Freezing

Data Source

PatentUS9080092B2Compositions for deicing/anti-icing
Publication Date: 2015.07.14 BATTELLE MEMORIAL INST
  • US9080092B2 patent drawing
  • US9080092B2 patent drawing
  • US9080092B2 patent drawing

AI summary

A non-toxic deicing/anti-icing fluid includes at least 20% by weight of a freeze point depressant selected from short chain polyols having 3 to 5 carbon atoms. The fluid further includes at least 10% by weight of water, a thickener, a surfactant, and a pH moderator. The fluid meets the requirements of SAE/AMS 1428 or its revisions for a non-Newtonian, Type II, III, or IV aircraft deicing/anti-icing fluid.