Deicing Composition Lignin Molasses Adhesion

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Solution Overview

Problem

Current deicing agents, such as sodium chloride, cause excessive damage to highly porous asphalt surfaces due to repeated freezing and thawing, leading to increased maintenance costs and safety hazards, as they are ineffective over a long period and tend to be washed away with meltwater.

Innovation Solution

A deicing composition combining a chloride salt (preferably sodium chloride or calcium chloride) with a lignin derivative and molasses, which enhances the deicing agent's adhesion and longevity, reducing damage to road surfaces by maintaining effectiveness over a longer period and minimizing corrosion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional deicing agents (sodium chloride, calcium chloride) are used on highly porous asphalt, then ice and snow are effectively melted, but the deicing agent is washed away with meltwater and remains ineffective over long periods

Engineering Contradiction:
Improvedeicing effectiveness durationVSAvoiddeicing agent washaway
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The patent introduces lignin derivatives and molasses as intermediary substances that form a film on the road surface. This film acts as a carrier for the deicing agent, preventing it from being washed away by meltwater. The lignin derivative (0.1-10 g/L) and molasses (1-100 g/L) create an adhesive layer that retains the deicing agent in contact with ice and snow throughout the melting process, thereby extending the effective duration of the deicing action.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates a composite deicing system combining conventional deicing agents (sodium chloride, calcium chloride, etc.) with organic additives (lignin derivatives and molasses). This composite formulation integrates the immediate ice-melting capability of inorganic salts with the film-forming and adhesive properties of organic substances, resulting in a multi-functional composition that both melts ice effectively and remains on the surface long enough to maintain effectiveness throughout the melting process.

Inventive Principle:
Principle #40Composite materials

2Reliability

If deicing agents are applied repeatedly to maintain effectiveness, then ice and snow are continuously controlled, but damage to asphalt surfaces increases due to repeated freezing and thawing cycles

Engineering Contradiction:
Improvecontinuous deicing protectionVSAvoidasphalt surface damage
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent achieves continuous deicing protection through a single application by forming a persistent film on the road surface. The lignin derivative and molasses create an adhesive layer that retains the deicing agent throughout the entire melting process, eliminating the need for repeated applications. This continuous action maintains ice and snow control while avoiding the cumulative damage that would result from multiple freeze-thaw cycles caused by repeated deicing agent applications.

Inventive Principle:
Principle #20Continuity of useful action

Solution Approach 2:

The patent converts the typically harmful effect of water penetration into porous asphalt (which causes freeze-thaw damage) into a beneficial mechanism. The lignin derivative and molasses formulation allows controlled water presence on the surface while preventing uncontrolled infiltration into the asphalt structure. The film-forming agents create a protective barrier that manages water interaction with the porous asphalt, reducing mechanical stress while maintaining deicing effectiveness.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Reliability

If higher concentrations of deicing agent are used to account for washaway, then effectiveness is maintained longer, but corrosion and environmental impact increase

Engineering Contradiction:
Improvedeicing effectiveness durationVSAvoidcorrosion
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent uses lignin derivatives and molasses as intermediary carriers that enable the use of lower concentrations of deicing agents. By forming an adhesive film that prevents washaway, the system achieves extended effectiveness with reduced salt quantities. This intermediary mechanism allows the deicing agent to remain in contact with ice and snow throughout the melting process, eliminating the need for excessive salt application that would otherwise be required to compensate for rapid washaway, thereby reducing corrosion and environmental harm.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The deicing composition with lignin derivative and molasses improves the deicing agent's performance, reducing damage to road surfaces by maintaining effectiveness and adhesion, thus requiring less frequent application and minimizing corrosion, while effectively melting ice and snow without causing excessive mechanical stress to the road surfaces.

Implementation Method 1

The sodium chloride works as a deicing agent by dissolving into precipitation on roadways and lowering the freezing point, thereby melting ice and snow.

Methodology Applied
Scientific EffectFreezing point depression:

Implementation Method 2

Due to better adhesion properties of the deicing composition compared to use of the deicing agent alone, less deicing agent is likely to be blown away and the deicing agent will be retained on the road for a longer period of time.

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 3

When the air/ground temperature becomes sufficiently low, an aqueous solution which is present in the channels of the asphalt will expand upon freezing, thus creating mechanical stress in the asphalt.

Methodology Applied
Scientific EffectThermal expansion: Thermal Expansion

Data Source

PatentEP2776528B1Deicing composition
Publication Date: 2017.10.18 AKZO NOBEL CHEMICALS INTERNATIONAL BV
  • EP2776528B1 patent drawing
  • EP2776528B1 patent drawing
  • EP2776528B1 patent drawing

AI summary

The present invention relates to a deicing composition comprising (i) a deicing agent selected from the group consisting of sodium chloride, calcium magnesium acetate, calcium chloride, magnesium chloride, potassium chloride, potassium acetate, sodium acetate, sodium formate, potassium formate, (ii) a lignin derivative, and (iii) molasses. It furthermore relates to a process for preparing said deicing composition and to a process for deicing a surface using said deicing composition.