Dendrimer Compound for Organic Luminescent Devices

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Solution Overview

Problem

There is a need for a novel dendrimer compound that can function effectively as both a luminescent material and a charge transport material for organic luminescent devices, as existing high molecular weight materials face limitations in solubility and structural versatility.

Innovation Solution

A dendrimer compound with a specific core structure and dendritic structure, characterized by the presence of aromatic rings, metal complex structures, and various linking groups, which can be used to form layers in organic luminescent devices, enhancing luminescence and charge transport capabilities.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If high molecular weight luminescent materials are used, then solubility is improved, but structural versatility deteriorates

Engineering Contradiction:
ImprovesolubilityVSAvoidstructural versatility
Core Design Contradiction:
Ease of manufactureVSAdaptability or versatility

Solution Approach 1:

The invention segments the high molecular weight material into dendrimer units with repeating structural motifs (generations of branching). This segmentation allows the material to maintain solubility characteristics of smaller units while achieving high molecular weight properties, resolving the contradiction between solubility and structural versatility

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The dendrimer structure employs nested branching generations where smaller dendritic units are incorporated into larger structures. This nested architecture enables systematic modification of structural versatility while maintaining solubility through the hierarchical organization of repeating units

Inventive Principle:
Principle #7Nested doll (Nesting)

2Power

If dendrimer compounds with specific structures are used, then luminescence efficiency is improved, but device complexity increases

Engineering Contradiction:
Improveluminescence efficiencyVSAvoidstructural complexity
Core Design Contradiction:
PowerVSDevice complexity

Solution Approach 1:

The invention optimizes luminescence efficiency by systematically varying dendrimer generation numbers and terminal group compositions. These parameter changes allow tuning of optical properties and charge transport characteristics without fundamentally altering the core dendrimer architecture, thus improving performance while controlling complexity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The dendrimer compound is designed to perform multiple functions simultaneously: luminescence emission, charge transport, and potential host-guest complexation. This multi-functionality reduces the need for separate materials layers, simplifying overall device structure despite the molecular complexity of the dendrimer itself

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The dendrimer compound improves the efficiency and performance of organic luminescent devices by providing effective luminescence and charge transport, enabling low-voltage and high-efficiency operation, suitable for applications in lighting, display devices, and solar cells.

Implementation Method 1

a dendrimer compound having a structure represented by the following formula (5) is useful as a luminescent material

Methodology Applied
Scientific EffectLuminescence: Luminescence

Implementation Method 2

a dendrimer compound having a structure represented by the following formula (5) is useful as a luminescent material and a charge transport material

Methodology Applied
Scientific EffectCharge transport: Conduction (electrical)

Data Source

PatentUS9966532B2Dendrimer compound and organic luminescent device employing the same
Publication Date: 2018.05.08 SUMITOMO CHEM CO LTD
  • US9966532B2 patent drawing
  • US9966532B2 patent drawing
  • US9966532B2 patent drawing

AI summary

A dendrimer compound characterized by comprising a core represented by the following formula (1-1), (1-2), (1-3), or (1-4) and at least one kind of dendritic structure selected among dendritic structures represented by the following formulae (3) and (4).