Filtration Membranes with Embedded Dendritic Nanoparticles

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Solution Overview

Problem

Current filtration technologies face challenges in developing efficient, cost-effective, and environmentally friendly methods for selective filtration, particularly in water treatment and desalination, as they often require high pressures and lack versatility in handling various contaminants.

Innovation Solution

Development of filtration membranes with embedded polymeric micro/nanoparticles, specifically using poly(vinylidinefluoride) (PVDF), polyamines, and acrylic polymers, which allow for in situ formation of dendritic nanoparticles within a polymer matrix, enabling low-pressure filtration and selective separation of ions and solutes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional reverse osmosis membranes are used for water treatment, then salt rejection is achieved, but high pressure is required which increases energy consumption and operational cost

Engineering Contradiction:
Improvesalt rejectionVSAvoidenergy consumption
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The patent employs nanofibrous scaffolds with controlled pore sizes and hierarchical pore structures to achieve selective ion rejection. The porous architecture allows water molecules to pass through while blocking larger solute molecules, enabling filtration without requiring high pressure systems typical of conventional reverse osmosis membranes.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The invention creates composite membranes by integrating nanofibrous scaffolds with separation layers containing crosslinked dendritic macromolecules. This composite structure combines the mechanical strength and porosity control of nanofibers with the selective separation capabilities of dendritic polymers, achieving effective salt rejection at lower pressures.

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If single-function polymeric membranes are used, then specific filtration task is performed, but versatility for handling various contaminants is limited

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidcontaminant handling capability
Core Design Contradiction:
Ease of manufactureVSAdaptability or versatility

Solution Approach 1:

The patent designs multifunctional membranes where nanofibrous scaffolds provide structural support and porosity control, while separation layers with crosslinked dendritic macromolecules deliver selective separation. This architecture enables a single membrane system to handle multiple contaminant types including salts, organic molecules, and colloidal particles, replacing the need for multiple specialized membranes.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Productivity

If high-pressure filtration systems are used, then filtration efficiency is improved, but operational cost and system complexity increase

Engineering Contradiction:
Improvefiltration efficiencyVSAvoidsystem complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The invention changes the fundamental operating parameter from high pressure to low-pressure operation by utilizing the intrinsic properties of nanofibrous materials and dendritic macromolecules. The nanofibers provide high surface area and controlled porosity, while the crosslinked dendritic structures create steric hindrance and selective interactions, enabling efficient filtration through concentration gradients rather than pressure gradients.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

These membranes facilitate efficient, cost-effective, and environmentally sound filtration processes, enabling the extraction of clean water and valuable chemicals from impaired water sources without the need for high pressures, and can be applied in various industrial and environmental separations, including water desalination and gas separations.

Implementation Method 1

separation layers consisting of crosslinked dendritic macromolecules

Methodology Applied
Scientific EffectSize exclusion:

Implementation Method 2

crosslinked dendritic macromolecules

Methodology Applied
Scientific EffectSteric hindrance:

Implementation Method 3

facilitate efficient, cost-effective, and environmentally sound filtration processes

Methodology Applied
Scientific EffectDiffusion: Diffusion

Data Source

PatentUS11090616B2Filtration membranes and related compositions, methods and systems
Publication Date: 2021.08.17 CALIFORNIA INST OF TECH
  • US11090616B2 patent drawing
  • US11090616B2 patent drawing
  • US11090616B2 patent drawing

AI summary

Described herein are filtration membranes and related, compositions, methods and systems and in particular filtration membranes with embedded polymeric micro/nanoparticles and related compositions, methods, and systems.