Dense-Membrane Gas Sensor for Fast Response and Stable Recovery

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Solution Overview

Problem

Conventional gas sensors with nano-gap electrodes exhibit quick response but require a long time to recover sensor characteristics, and the mechanism for enhancing responsiveness is not well understood.

Innovation Solution

A gas sensor design featuring electrode pairs with a dense sensitive membrane between electrodes, formed through physical or chemical vapor deposition, and subjected to heat treatment, facilitating easy electron movement in depletion layers.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If a conventional chemical sensor with micrometer-scale electrodes is used, then the sensor structure is simple and easy to manufacture, but the responsiveness is poor and long time is needed for concentration detection

Engineering Contradiction:
ImproveresponsivenessVSAvoidelectrode structure complexity
Core Design Contradiction:
SpeedVSDevice complexity

Solution Approach 1:

The patent changes the critical parameter of inter-electrode distance from micrometer scale to nanometer scale (10-100 nm), transforming the sensor's responsiveness. This parameter change enables faster electron tunneling and signal generation, achieving real-time measurement capability while maintaining reasonable structural complexity through controlled fabrication processes

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces a sensitive membrane with specific local properties (porosity, thickness, material composition) between the electrodes to enhance gas sensitivity and electron transport. This local quality enhancement focuses the sensor's detection capability at the critical interface where gas molecules interact with the electrode structure

Inventive Principle:
Principle #3Local quality

2Speed

If nano-gap electrodes are used to improve responsiveness, then quick response is achieved, but a long time is needed to recover sensor characteristics and the mechanism is not well understood

Engineering Contradiction:
Improveresponse speedVSAvoidsensor characteristic recovery
Core Design Contradiction:
SpeedVSReliability

Solution Approach 1:

The patent employs a sensitive membrane with controlled porosity (30-70%) that facilitates both rapid gas diffusion and electron transport. The porous structure provides pathways for gas molecules to reach active sites while maintaining electrical connectivity, enabling quick response and reliable recovery by balancing mass transport and charge transport mechanisms

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The sensitive membrane acts as an intermediary layer between the electrodes and the target gas. This intermediate structure mediates the interaction by providing a controlled interface for gas adsorption and electron transfer, improving both response speed and recovery reliability through its catalytic and conductive properties

Inventive Principle:
Principle #24Intermediary (Mediator)

3Speed

If the inter-electrode distance is reduced to several nanometers, then responsiveness is improved, but manufacturing precision requirements increase significantly

Engineering Contradiction:
ImproveresponsivenessVSAvoidinter-electrode gap control
Core Design Contradiction:
SpeedVSManufacturing precision

Solution Approach 1:

The patent replaces conventional mechanical positioning methods with deposition-based techniques (such as atomic layer deposition or sputtering) to form the sensitive membrane and control electrode spacing. This substitution of manufacturing approaches enables precise control of nanometer-scale gaps through material deposition thickness control rather than mechanical machining, achieving both high responsiveness and manufacturability

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enhances responsiveness by reducing contact resistance and enabling stable, rapid signal output through electron conduction paths.

Implementation Method 1

the sensitive membrane is formed by means of physical vapor deposition or chemical vapor deposition

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Implementation Method 2

the sensitive membrane is formed by means of physical vapor deposition or chemical vapor deposition

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Implementation Method 3

heat treatment is performed for the sensitive membrane after being formed

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Implementation Method 4

a voltage application section which applies a voltage to the electrode portion such that the voltage is applied between the first electrode and the second electrode

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Data Source

PatentUS20250264437A1Gas sensor and method for manufacturing gas sensor
Publication Date: 2025.08.21 NITERRA CO LTD
  • US20250264437A1 patent drawing
  • US20250264437A1 patent drawing
  • US20250264437A1 patent drawing

AI summary

A gas sensor characterized by including an electrode portion which includes one or more electrode pairs each having a first electrode and a second electrode, the first electrode and the second electrode being opposed to each other in a first direction in the electrode pair, with a gap formed therebetween, a sensitive membrane disposed between the first electrode and the second electrode in the electrode pair, and a voltage application section which applies a voltage to the electrode portion such that the voltage is applied between the first electrode and the second electrode. The sensitive membrane is a dense body.