Cryopreservation method and apparatus

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Solution Overview

Problem

Current cryopreservation techniques, such as controlled cooling, result in ice crystal formation, causing damage to biological samples, especially tissues and organs, and are unsuitable for preserving larger samples due to ice damage, while vitrification methods face challenges with rapid cooling rates and cryoprotectant toxicity, limiting their effectiveness for larger biological samples.

Innovation Solution

A method involving density-assisted vitrification where the top surface of a biological sample is cooled to form an ice layer, allowing the underlying sample to solidify as glass, using a thermally conducting member to homogenize temperature and progressively form ice from the top surface towards the base, with controlled cooling rates and additional cryoprotectant addition to enhance cryopreservation, facilitated by a cryopreservation apparatus with controlled cooling and agitation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Duration of action of stationary object

If controlled cooling is used to preserve biological samples, then samples can be stored at low temperatures, but ice crystals form and cause damage to the samples

Engineering Contradiction:
Improvestorage durationVSAvoidice crystal damage
Core Design Contradiction:
Duration of action of stationary objectVSObject-affected harmful factors

Solution Approach 1:

The patent changes the cooling rate parameter from conventional slow cooling to extremely rapid cooling (vitrification), transforming the physical state of water from crystalline ice to amorphous glass, thereby eliminating ice crystal formation while maintaining long-term storage capability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite cryoprotectant formulations combining multiple agents (e.g., DMSO, glycerol, sugars) to achieve both rapid vitrification and cellular protection, creating a composite preservation system that prevents ice damage while maintaining sample integrity

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If vitrification is used to avoid ice crystal formation, then samples are preserved without ice damage, but extremely rapid cooling rates are required which are difficult to achieve for larger samples

Engineering Contradiction:
Improveice damageVSAvoidcooling rate
Core Design Contradiction:
Object-affected harmful factorsVSSpeed

Solution Approach 1:

The patent segments the cooling process into controlled stages and uses segmented cryoprotectant application, allowing large samples to be vitrified by treating different regions sequentially rather than requiring uniform extreme cooling across the entire sample simultaneously

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent introduces cryoprotectant agents as intermediary substances that mediate the phase transition of water, allowing vitrification to occur at more manageable cooling rates by chemically modifying the water structure and preventing ice nucleation

Inventive Principle:
Principle #24Intermediary (Mediator)

3Object-affected harmful factors

If cryoprotectants are added to prevent ice formation, then ice damage is reduced, but cryoprotectant toxicity affects the biological samples

Engineering Contradiction:
Improveice damageVSAvoidcryoprotectant toxicity
Core Design Contradiction:
Object-affected harmful factorsVSObject-generated harmful factors

Solution Approach 1:

The patent optimizes cryoprotectant concentration parameters and exposure time parameters, using lower concentrations combined with rapid vitrification to achieve protection while minimizing toxic effects, and controls temperature parameters to reduce toxicity during the preservation process

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite cryoprotectant formulations that combine multiple agents with different mechanisms of action, allowing lower overall concentrations to be used while achieving equivalent or superior protection, thereby reducing individual agent toxicity

Inventive Principle:
Principle #40Composite materials

4Volume of stationary object

If conventional cryopreservation is used for large samples, then samples can be preserved, but ice crystals form and cause irreparable damage

Engineering Contradiction:
Improvesample sizeVSAvoidice crystal damage
Core Design Contradiction:
Volume of stationary objectVSObject-affected harmful factors

Solution Approach 1:

The patent fundamentally changes the thermal processing parameters from conventional slow cooling to rapid vitrification cooling, and adjusts chemical parameters by using optimized cryoprotectant formulations, enabling large samples to be preserved without ice crystal formation

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies cryoprotectants to samples in advance before the vitrification process, allowing sufficient time for penetration and protection of large sample volumes, and pre-cools equipment and environment to facilitate rapid cooling when the sample is introduced

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables effective cryopreservation of larger biological samples by minimizing ice damage, achieving vitrification without extreme cooling rates or pressure, and allowing for the preservation of samples greater than 1 mm³, maintaining structural and functional integrity.

Implementation Method 1

cooling the top surface of the sample to selectively form an ice layer at the top surface of the sample

Methodology Applied
Scientific EffectFreezing: Freezing

Implementation Method 2

cooling progresses through a thermally conducting member, which is preferably located centrally of the sample liquid, which homogenises the temperature in the majority of the sample's remaining liquid component

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Implementation Method 3

a layer of the sample below the ice layer solidifies as a glass, thus delivering a vitrified composition of biological material in the cryopreservation medium

Methodology Applied
Scientific EffectVitrification: Vitrification

Data Source

PatentEP3694321B1Cryopreservation method and apparatus
Publication Date: 2023.09.13 ASYMPTOTE
  • EP3694321B1 patent drawingFigure 1
  • EP3694321B1 patent drawingFigure 2
  • EP3694321B1 patent drawingFigure 3

AI summary

The present invention relates to methods and apparatus for the cryopreservation of biological samples involving a density assisted vitrification wherein a sample of biological material in a cryopreservation agent is cooled from its top surface, causing an ice layer to form thereon. As cooling continues the ice layer grows downwards through the sample to provide a cryoprotectant and biological material rich layer below the ice layer that undergoes vitrification as cooling continues to below the glass transition temperature.