Denture Adhesive Copolymer Salt Composition for Taste and Hold

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Solution Overview

Problem

Existing denture adhesives face challenges with inadequate holding power, messiness, difficulty in removing residual adhesive, and undesirable taste, despite previous developments using alkyl vinyl ether-maleic copolymers and their salts.

Innovation Solution

A denture adhesive composition comprising salts of alkyl vinyl ether-maleic acid copolymers with specific ratios of calcium, strontium, and magnesium salts, combined with carboxymethyl cellulose and controlled levels of free acid, providing improved adhesion and taste.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional denture adhesives are used, then basic adhesion is provided, but holding power is inadequate

Engineering Contradiction:
Improveholding powerVSAvoidadhesion reliability
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies parameter changes by optimizing the molecular weight of the copolymer (1,000,000 to 3,000,000), controlling the alkyl group size (C1-C5), and adjusting the salt composition ratios to achieve superior adhesion strength and holding power compared to conventional adhesives

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite materials by combining alkyl vinyl ether-maleic copolymers with specific metal salts (calcium, strontium, magnesium) and carboxymethyl cellulose to create a multi-component adhesive system that provides enhanced and reliable holding power

Inventive Principle:
Principle #40Composite materials

2Reliability

If traditional adhesive formulations are used, then adhesion is provided, but messiness occurs

Engineering Contradiction:
Improveadhesion effectivenessVSAvoidmessiness
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent employs carboxymethyl cellulose as a flexible film-forming agent that creates a thin, cohesive adhesive layer, reducing messiness while maintaining effective adhesion between the denture and oral tissues

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The composite formulation combining copolymer salts with carboxymethyl cellulose creates a cohesive adhesive matrix that minimizes residue and messiness while providing reliable adhesion

Inventive Principle:
Principle #40Composite materials

3Duration of action of stationary object

If residual adhesive remains in the mouth, then adhesion is maintained, but difficulty in removing residual adhesive occurs

Engineering Contradiction:
Improveadhesion durationVSAvoidease of removal
Core Design Contradiction:
Duration of action of stationary objectVSEase of operation

Solution Approach 1:

The patent facilitates easy removal by designing an adhesive system that can be cleanly extracted from the oral cavity, with the copolymer and carboxymethyl cellulose formulation allowing for complete removal without stubborn residue

Inventive Principle:
Principle #2Taking out (Extraction)

4Reliability

If certain adhesive components are used, then adhesion is provided, but undesirable taste is generated

Engineering Contradiction:
Improveadhesion performanceVSAvoidtaste quality
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent improves taste quality by carefully selecting and controlling the metal salt composition (calcium, strontium, magnesium ratios) and eliminating zinc salts, which are known to produce undesirable metallic tastes, while maintaining effective adhesion performance

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves enhanced adhesion, reduced messiness, and improved taste by optimizing the cationic salt function and free acid content, ensuring secure denture fit and user satisfaction.

Implementation Method 1

The denture stabilizer is formulated not only for its adherent properties, but also to provide a cushion or gasket between the denture and the gums or tissues

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 2

from about 15% to about 25%, by weight of the composition of a carboxymethyl cellulose having a molecular weight of from about 200,000 to about 1,000,000 daltons

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Data Source

PatentUS9463145B2Denture adhesive compositions
Publication Date: 2016.10.11 PROCTER & GAMBLE CO
  • US9463145B2 patent drawing

AI summary

Denture adhesive compositions having good hold and improved taste containing a salt of a copolymer of alkyl vinyl ether-maleic acid or anhydride. Compositions containing from about 25% to about 45%, by weight of the composition, of a salt of a copolymer of alkyl vinyl ether-maleic acid or anhydride containing a cationic salt function containing: i) from about 60% to about 72% cations selected from calcium, strontium, magnesium, or combinations thereof; ii) from 0% to about 10% sodium cations; iii) less than 1% zinc cations; and iv) from about 25% to about 40% of a free acid component; and further containing from about 15% to about 25%, by weight of the composition of a carboxymethyl cellulose having a molecular weight of from about 200,000 to about 1,000,000 daltons; and a carrier. Methods of improving the adhesion of dentures to the oral cavity by applying such compositions to dentures, the oral cavity, or both, and thereafter securing the denture to the ridge or palate of the oral cavity.