Desalination via Concentration Difference Energy

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Solution Overview

Problem

Current desalination methods, such as reverse osmosis, multiple effect distillation, and electrodialysis, face challenges with high energy consumption, performance issues with warm seawater, and inefficiencies due to voltage gradients and ion migration, limiting their effectiveness in providing freshwater for populations lacking access.

Innovation Solution

A desalination apparatus and method utilizing a plurality of drive cells with ion exchange membranes to generate a drive voltage from concentration differences between diluent and concentrate solutions, allowing for energy-efficient desalination without external power sources, reducing ion migration losses, and maintaining performance across varying temperatures.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If reverse osmosis is used for desalination, then desalination can be achieved, but energy consumption increases and performance deteriorates when temperature exceeds 30°C

Engineering Contradiction:
Improvedesalination performanceVSAvoidenergy consumption
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

The patent replaces the mechanical pressure-driven reverse osmosis system with an electrochemical system using ion exchange membranes and applied voltage. This substitution eliminates the mechanical compression requirements and allows desalination to proceed effectively at higher temperatures where reverse osmosis fails, while reducing overall energy consumption through more efficient ion transport mechanisms.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the operating parameters by applying voltage across ion exchange membranes rather than applying mechanical pressure. This parameter change enables the system to maintain effective desalination performance at temperatures above 30°C, overcoming the temperature limitation of reverse osmosis while consuming less energy through the electrochemical mechanism.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If electrodialysis is used for desalination, then desalination can be achieved, but energy consumption increases and ion migration losses occur

Engineering Contradiction:
Improvedesalination capabilityVSAvoidenergy consumption
Core Design Contradiction:
ReliabilityVSLoss of energy

Solution Approach 1:

The patent extracts and eliminates the need for external DC power sources and rectifiers by utilizing the natural concentration difference between feed and product streams. The system harnesses the inherent electrochemical potential from the saltwater concentration gradient to drive ion transport through ion exchange membranes, removing the energy loss associated with external power conversion and reduction.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The system performs self-service by using the saltwater concentration difference itself as the energy source. The feed solution's higher salt concentration naturally provides the electrochemical potential needed to drive desalination, eliminating the need for external energy input and associated losses from power conversion hardware.

Inventive Principle:
Principle #25Self-service

3Reliability

If electrodialysis is used for desalination, then desalination can be achieved, but voltage gradients cause ion migration through manifolding reducing efficiency

Engineering Contradiction:
Improveion separationVSAvoiddesalination efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent segments the ion transport process into discrete compartments using alternating cation-exchange and anion-exchange membranes. This segmentation creates a structured pathway that prevents voltage gradients from causing unwanted ion migration through manifolding, as each membrane layer selectively transports ions in controlled directions through the segmented structure.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent introduces ion exchange membranes as intermediary elements between the feed solution and product solution. These membranes act as selective mediators that facilitate controlled ion transport while blocking the pathways that would otherwise allow voltage-gradient-driven ion migration through the manifolding structure, thereby maintaining desalination efficiency.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Reliability

If multiple effect distillation is used for desalination, then desalination can be achieved, but thermal energy consumption increases

Engineering Contradiction:
Improvedesalination processVSAvoidthermal energy consumption
Core Design Contradiction:
ReliabilityVSUse of energy by stationary object

Solution Approach 1:

The patent replaces the thermal-based distillation process with an electrochemical process using ion exchange membranes and applied voltage. This substitution eliminates the need for continuous thermal energy input to drive evaporation and condensation cycles, achieving desalination through electrochemical ion transport that consumes significantly less energy.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent avoids relying on phase transitions (evaporation and condensation) that consume large amounts of thermal energy. Instead, it uses ion exchange membranes to directly separate ions from water through electrochemical potential differences, eliminating the need for phase change cycles and associated thermal energy consumption.

Inventive Principle:
Principle #36Phase transitions

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enables energy-efficient desalination of saltwater using readily accessible low-temperature energy, reducing capital costs, and improving efficiency by minimizing ion migration and pre-treatment requirements, while maintaining performance with warm seawater.

Implementation Method 1

a plurality of drive cells for generating a drive voltage, each drive cell having a diluent chamber for containing a diluent of a first ionic concentration, a concentrate chamber for containing a concentrate of a second ionic concentration that is greater than the first ionic concentration, one of a cation or anion exchange membrane forming a shared boundary between and in ionic communication with the diluent and concentrate chambers

Methodology Applied
Scientific EffectIon Exchange: Ion Exchange

Implementation Method 2

utilizing the energy difference that exists between two solutions of different solute concentrations that are separated by an ion exchange membrane

Methodology Applied
Scientific EffectConcentration difference energy: Nernst Effect

Data Source

PatentUS8137522B2Method for desalinating saltwater using concentration difference energy
Publication Date: 2012.03.20 SALTWORKS TECHNOLOGIES INC
  • US8137522B2 patent drawing
  • US8137522B2 patent drawing
  • US8137522B2 patent drawing

AI summary

A method and apparatus for desalinating saltwater using concentration difference energy is disclosed. In order to desalinate saltwater that is contained within a product chamber, a drive cell is used to generate a drive voltage. The product chamber has a desalination voltage such that when a sufficient voltage is applied to the product chamber, anions and cations migrate out of the product chamber, thereby desalinating the water. The sufficient voltage, which includes the drive voltage and which is equal to or greater than the desalination voltage, is applied to the product chamber, consequently effecting desalination. Beneficially, concentration difference energy can be generated using a concentrated solution, which can be generated using, for example, solar energy.